Synthesis and physicochemical characterization of rhenium(V) complexes with bisbenzoylthiosemicarbazones

被引：0
|
作者：
Gagieva, SC [1 ]
Gutnova, NA [1 ]
Tsaloev, AT [1 ]
Khubulov, AB [1 ]
Arutyunyants, AA [1 ]
Gallimov, YB [1 ]
机构：
[1] No Ossetian State Univ, Vladikavkaz, No Ossetia, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 48卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhenium(V) complexing with mono- and bisbenzoylthiosemicarbazones has been studied as a function of hydrohaloic acid (Mal HCl, HBr) concentration. Given a high acid concentration (6 M HCl, 7 M HBr). stable coordination compounds with bidentate- or tridentate-coordinated semicarbazone are formed depending on the reaction conditions. At lower acid concentrations, stable binuclear and hydroxooxo complexes are formed. The composition and structure of the complexes have been determined using elemental analysis, IR spectroscopy, and conductometry. A thermal study of the complexes has been carried out.
引用
收藏
页码：687 / 692
页数：6
相关论文
共 50 条
  • [1] Synthesis and physicochemical characterization of rhenium(V) complexes with benzimidazole
    Gagieva, SC
    Tsaloev, AT
    Gutnova, NA
    Arutyunyants, AA
    Khubulov, AB
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (08) : 1182 - 1184
  • [2] Synthesis and physicochemical properties of rhenium(V) complexes with mercaptobenzothiazole
    Gagieva, SC
    Gutnova, NA
    Tsaloev, AT
    Khubulov, AB
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (12) : 1876 - 1880
  • [3] Synthesis and physicochemical properties of rhenium(V) complexes with benzimidazole
    Gagieva, S.Ch.
    Tsaloev, A.T.
    Gutnova, N.A.
    Arutyunyants, A.A.
    Khubulov, A.B.
    [J]. Zhurnal Neorganicheskoj Khimii, 2003, 48 (08): : 1303 - 1307
  • [4] Synthesis and characterization of rhenium(III) and (V) pyridylimidazole complexes
    Gerber, TIA
    Hosten, E
    Mayer, P
    Tshentu, ZR
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (03) : 243 - 253
  • [5] Synthesis and physicochemical study of rhenium(V) complexes with phenylglyoxylic acid thiosemicarbazone
    Gagieva, S.Ch.
    Tsaloev, A.T.
    Gutnova, N.A.
    Galimov, Yu.B.
    Chel'dieva, G.M.
    Turieva, A.A.
    [J]. Zhurnal Neorganicheskoj Khimii, 2002, 47 (05): : 815 - 819
  • [6] Synthesis and physicochemical study of rhenium(V) complexes with phenylglyoxylic acid thiosemicarbazone
    Gagieva, SC
    Tsaloev, AT
    Gutnova, NA
    Galimov, YB
    Chel'dieva, GM
    Turieva, AA
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (05) : 724 - 727
  • [7] Synthesis, characterization and crystal structures of rhenium(V) complexes with diphosphines
    Kremer, C
    Rivero, M
    Kremer, E
    Suescun, L
    Mombrú, AW
    Mariezcurrena, R
    Domínguez, S
    Mederos, A
    Midollini, S
    Castiñeiras, A
    [J]. INORGANICA CHIMICA ACTA, 1999, 294 (01) : 47 - 55
  • [8] SYNTHESIS AND CHARACTERIZATION OF OXOPENTAKIS(ISOTHIOCYANATO)METALATE(V) COMPLEXES OF RHENIUM AND TECHNETIUM
    DAVISON, A
    JONES, AG
    MULLER, L
    TATZ, R
    TROP, HS
    [J]. INORGANIC CHEMISTRY, 1981, 20 (04) : 1160 - 1163
  • [9] SYNTHESIS AND CHARACTERIZATION OF RHENIUM COMPLEXES WITH SALICYLALDEHYDE
    DUATTI, A
    ROSSI, R
    MARCHI, A
    PASQUETTO, A
    MAZZI, U
    [J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 81 (01): : 21 - 24
  • [10] SYNTHESIS AND CHARACTERIZATION OF RHENIUM DIHYDROGEN COMPLEXES
    HEINEKEY, DM
    RADZEWICH, CE
    SCHOMBER, BM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 249 - INOR
12345