Synthesis and physicochemical characterization of rhenium(V) complexes with bisbenzoylthiosemicarbazones

被引：0
|
作者：
Gagieva, SC [1 ]
Gutnova, NA [1 ]
Tsaloev, AT [1 ]
Khubulov, AB [1 ]
Arutyunyants, AA [1 ]
Gallimov, YB [1 ]
机构：
[1] No Ossetian State Univ, Vladikavkaz, No Ossetia, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 48卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhenium(V) complexing with mono- and bisbenzoylthiosemicarbazones has been studied as a function of hydrohaloic acid (Mal HCl, HBr) concentration. Given a high acid concentration (6 M HCl, 7 M HBr). stable coordination compounds with bidentate- or tridentate-coordinated semicarbazone are formed depending on the reaction conditions. At lower acid concentrations, stable binuclear and hydroxooxo complexes are formed. The composition and structure of the complexes have been determined using elemental analysis, IR spectroscopy, and conductometry. A thermal study of the complexes has been carried out.
引用
收藏
页码：687 / 692
页数：6
相关论文
共 50 条
  • [21] SYNTHESIS AND CHARACTERIZATION OF (ORTHO-PHENYLENEBIS(DIMETHYLARSINE))RHENIUM(III) AND (V) COMPLEXES WITH THIOLATO LIGANDS
    CHANG, LS
    HEEG, MJ
    DEUTSCH, E
    [J]. INORGANIC CHEMISTRY, 1994, 33 (08) : 1614 - 1621
  • [22] The synthesis and characterization of technetium and rhenium hydrazinopyrimidine chelate complexes
    HirschKuchma, M
    Nicholson, T
    Davison, A
    Davis, WM
    Jones, AG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18): : 3185 - 3188
  • [23] SYNTHESIS AND CHARACTERIZATION OF SECONDARY CARBENE COMPLEXES OF MANGANESE AND RHENIUM
    GIBSON, DH
    MANDAL, SK
    OWENS, K
    RICHARDSON, JF
    [J]. ORGANOMETALLICS, 1990, 9 (06) : 1936 - 1942
  • [24] SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF SOME RHENIUM PHOSPHITE COMPLEXES
    RHODES, LF
    CAULTON, KG
    RYBAK, WK
    ZIOLKOWSKI, JJ
    [J]. POLYHEDRON, 1986, 5 (11) : 1891 - 1893
  • [25] Synthesis and characterization of functionalized rhenium imido complexes.
    Arterburn, JB
    Hall, KA
    Fogarty, IM
    Goreham, DM
    Bryan, JC
    Ott, KC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 548 - INOR
  • [26] SYNTHESIS, CHARACTERIZATION AND PHYSICOCHEMICAL PROPERTIES OF PEROXO-VANADIUM(V) COMPLEXES WITH GLYCINE AS THE HETEROLIGAND
    BHATTACHARJEE, M
    CHAUDHURI, MK
    ISLAM, NS
    PAUL, PC
    [J]. INORGANICA CHIMICA ACTA, 1990, 169 (01) : 97 - 100
  • [27] SYNTHESIS AND CHARACTERIZATION OF NEW ACETYLENE COMPLEXES OF MANGANESE AND RHENIUM
    ALT, HG
    ENGELHARDT, HE
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 342 (02) : 235 - 241
  • [28] SYNTHESIS AND CHARACTERIZATION OF RHENIUM(VII) OXIDE COMPLEXES OF PHENOTHIAZINES
    GOWDA, NMM
    PHYU, HP
    ACKERSON, BE
    [J]. TRANSITION METAL CHEMISTRY, 1993, 18 (01) : 64 - 68
  • [29] Synthesis and reactions of rhenium(V) oxo-hydride complexes
    Matano, Y
    Brown, SN
    Northcutt, TO
    Mayer, JM
    [J]. ORGANOMETALLICS, 1998, 17 (14) : 2939 - 2941
  • [30] SYNTHESIS AND OXIDATION OF RHENIUM(V) OXO ALKYL AND ALKOXIDE COMPLEXES
    DUMEZ, DD
    MAYER, JM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 258 - INOR
12345