The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

被引：95

作者：

Wang, Xu-Zhe ^{[1
]}

Meng, Qing-Yuan

Zhong, Jian-Ji

Gao, Xue-Wang

Lei, Tao

Zhao, Lei-Min

Li, Zhi-Jun

Chen, Bin

Tung, Chen-Ho

Wu, Li-Zhu ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 56期

基金：

中国国家自然科学基金;

关键词：

ORGANIC TRIPLET PHOTOSENSITIZERS; HYDROGEN EVOLUTION REACTION; HIGHLY EFFICIENT; FLUORESCENT-PROBE; DESIGN; PHOTOCATALYST; DERIVATIVES; OXIDATION; DYES;

D O I：

10.1039/c5cc03421c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to previous studies, we disclose for the first time that the singlet excited state ((PS)-P-1*) of BODIPY rather than the triplet excited state ((PS)-P-3*) can drive C-H bond activation to form C-C and C-P bonds smoothly, which offers new methods to promote organic transformation under visible light irradiation.

引用

页码：11256 / 11259

页数：4

共 50 条

[1] Visible-light induced Cross-Dehydrogenative-Coupling (CDC) reactions of N-aryl tetrahydroisoquinolines under aerobic conditions
Lin, Chao
Li, Peiwu
Wang, Lin
[J]. TETRAHEDRON LETTERS, 2021, 73
[2] Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions
Itazaki, Masumi
Nakazawa, Hiroshi
[J]. IRON CATALYSIS II, 2015, 50 : 47 - 81
[3] A Porous and Stable Porphyrin Metal-Organic Framework as an Efficient Catalyst towards Visible-Light-Mediated Aerobic Cross-Dehydrogenative-Coupling Reactions
Liu, Jiewei
Zhang, Kun
Chen, Zhiyao
Wei, Zhang-Wen
Zhang, Li
[J]. CHEMISTRY-AN ASIAN JOURNAL, 2020, 15 (07) : 1118 - 1124
[4] Visible light promoted cross-dehydrogenative coupling: a decade update
Bagdi, Avik Kumar
Rahman, Matiur
Bhattacherjee, Dhananjay
Zyryanov, Grigory V.
Ghosh, Sumit
Chupakhin, Oleg N.
Hajra, Alakananda
[J]. GREEN CHEMISTRY, 2020, 22 (20) : 6632 - 6681
[5] A visible-light-promoted cross-dehydrogenative-coupling reaction of N-arylglycine esters with imidazo[1,2-a]pyridines
Zhu, Zhi-Qiang
Xiao, Li-Jin
Zhou, Chun-Cheng
Song, Han-Lin
Xie, Zong-Bo
Le, Zhang-Gao
[J]. TETRAHEDRON LETTERS, 2018, 59 (35) : 3326 - 3331
[6] Rose-Bengal-Photocatalyzed Cross-Dehydrogenative Coupling Reactions under Visible Light
Patel, Divyani P.
Kumar Singh, Satish
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (08)
[7] Robust Metal-Organic Framework Containing Benzoselenadiazole for Highly Efficient Aerobic Cross-dehydrogenative Coupling Reactions under Visible Light
Zhang, Wen-Qiang
Li, Qiu-Yan
Zhang, Quan
Lu, Yingqiao
Lu, Han
Wang, Wenguang
Zhao, Xinsheng
Wang, Xiao-Jun
[J]. INORGANIC CHEMISTRY, 2016, 55 (03) : 1005 - 1007
[8] Visible-light-enabled cascade cross-dehydrogenative-coupling/cyclization to construct α-chromone substituted α-amino acid derivatives
Zhu, Zhi-Qiang
Hu, Jia-Yu
Xie, Zong-Bo
Le, Zhang-Gao
[J]. CHEMICAL COMMUNICATIONS, 2023, 60 (01) : 106 - 109
[9] A Highly Efficient and Selective Aerobic Cross-Dehydrogenative-Coupling Reaction Photocatalyzed by a Platinum(II) Terpyridyl Complex
Zhong, Jian-Ji
Meng, Qing-Yuan
Wang, Ge-Xia
Liu, Qiang
Chen, Bin
Feng, Ke
Tung, Chen-Ho
Wu, Li-Zhu
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (20) : 6443 - 6450
[10] Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols
Wang, Xianya
Xia, Chungu
Wu, Lipeng
[J]. ORGANIC LETTERS, 2020, 22 (18) : 7373 - 7377

← 1 2 3 4 5 →