Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions

被引：20

作者：

Itazaki, Masumi ^{[1
]}

Nakazawa, Hiroshi ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, 3-3-138 Sugimoto, Osaka 5588585, Japan

来源：

IRON CATALYSIS II | 2015年 / 50卷

关键词：

Catalyst; Iron; Cross-dehydrogenative coupling; Oxidant; Radical; C-H BOND; N-SULFONYL ALDIMINES; STUDIEN ZUM ABLAUF; CDC REACTION; HETEROAROMATIC BASES; ACTIVATION; ALKYLATION; SUBSTITUTIONS; ARYLATION; COMPLEX;

D O I：

10.1007/3418_2015_105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cross-dehydrogenative-coupling (CDC) reactions involving C-H bond activation are powerful tools for C-C bond formation and are highly significant from the perspective of atom economy. A variety of carbon-carbon bond-forming reactions utilizing various coupling partners are known today. Iron-catalyzed organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter summarizes the development of iron-catalyzed CDC reactions, the reaction mechanism, and the role of the Fe species in the catalytic cycle in the period from 2007 to 2014.

引用

页码：47 / 81

页数：35

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