Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions

被引：20

作者：

Itazaki, Masumi ^{[1
]}

Nakazawa, Hiroshi ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, 3-3-138 Sugimoto, Osaka 5588585, Japan

来源：

IRON CATALYSIS II | 2015年 / 50卷

关键词：

Catalyst; Iron; Cross-dehydrogenative coupling; Oxidant; Radical; C-H BOND; N-SULFONYL ALDIMINES; STUDIEN ZUM ABLAUF; CDC REACTION; HETEROAROMATIC BASES; ACTIVATION; ALKYLATION; SUBSTITUTIONS; ARYLATION; COMPLEX;

D O I：

10.1007/3418_2015_105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cross-dehydrogenative-coupling (CDC) reactions involving C-H bond activation are powerful tools for C-C bond formation and are highly significant from the perspective of atom economy. A variety of carbon-carbon bond-forming reactions utilizing various coupling partners are known today. Iron-catalyzed organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter summarizes the development of iron-catalyzed CDC reactions, the reaction mechanism, and the role of the Fe species in the catalytic cycle in the period from 2007 to 2014.

引用

页码：47 / 81

页数：35

共 50 条

[11] Ate Complexes in Iron-Catalyzed Cross-Coupling Reactions
Parchomyk, Tobias
Koszinowski, Konrad
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (44) : 15609 - 15613
[12] Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines
Lane, Elizabeth M.
Hazari, Nilay
Bernskoetter, Wesley H.
[J]. CHEMICAL SCIENCE, 2018, 9 (16) : 4003 - 4008
[13] Iron-catalyzed oxidative dehydrogenative coupling of ethers with aryl tetrazoles
Zhu, Kai-qiang
Wang, Liang
Chen, Qun
He, Ming-yang
[J]. TETRAHEDRON LETTERS, 2015, 56 (34) : 4943 - 4946
[14] New insights into the mechanism of iron-catalyzed cross-coupling reactions
Bekhradnia, Ahmadreza
Norrby, Per-Ola
[J]. DALTON TRANSACTIONS, 2015, 44 (09) : 3959 - 3962
[15] Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions
Czaplik, Waldemar Maximilian
Mayer, Matthias
Cvengros, Jan
Jacobi von Wangelin, Axel
[J]. CHEMSUSCHEM, 2009, 2 (05) : 396 - 417
[16] Iron-catalyzed cross-dehydrogenative C-N coupling of thiohydantoins with various amines
Mudaliar, Sulochana S.
Patel, Anuj P.
Patel, Janki J.
Chikhalia, Kishor H.
[J]. TETRAHEDRON LETTERS, 2018, 59 (08) : 734 - 738
[17] Iron-Catalyzed Cross Dehydrogenative Coupling (CDC) of Indoles and Benzylic C-H Bonds
Guo, Shuaibo
Li, Yaxuan
Wang, Yu
Guo, Xin
Meng, Xu
Chen, Baohua
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (05) : 950 - 954
[18] Iron-Catalyzed Hetero-Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines
Cheng, Ying
Dong, Wanrong
Wang, Long
Parthasarathy, Kanniyappan
Bolm, Carsten
[J]. ORGANIC LETTERS, 2014, 16 (07) : 2000 - 2002
[19] Mechanistic Investigation of Iron-Catalyzed Coupling Reactions
Kleimark, Jonatan
Hedstrom, Anna
Larsson, Per-Fredrik
Johansson, Charlotte
Norrby, Per-Ola
[J]. CHEMCATCHEM, 2009, 1 (01) : 152 - 161
[20] Iron-catalyzed domino coupling reactions of π-systems
Pounder, Austin
Tam, William
[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2021, 17 : 2848 - 2893

← 1 2 3 4 5 →