The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

被引：95

作者：

Wang, Xu-Zhe ^{[1
]}

Meng, Qing-Yuan

Zhong, Jian-Ji

Gao, Xue-Wang

Lei, Tao

Zhao, Lei-Min

Li, Zhi-Jun

Chen, Bin

Tung, Chen-Ho

Wu, Li-Zhu ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 56期

基金：

中国国家自然科学基金;

关键词：

ORGANIC TRIPLET PHOTOSENSITIZERS; HYDROGEN EVOLUTION REACTION; HIGHLY EFFICIENT; FLUORESCENT-PROBE; DESIGN; PHOTOCATALYST; DERIVATIVES; OXIDATION; DYES;

D O I：

10.1039/c5cc03421c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to previous studies, we disclose for the first time that the singlet excited state ((PS)-P-1*) of BODIPY rather than the triplet excited state ((PS)-P-3*) can drive C-H bond activation to form C-C and C-P bonds smoothly, which offers new methods to promote organic transformation under visible light irradiation.

引用

页码：11256 / 11259

页数：4

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