Synthesis and Structure of a Thiocyanato-Bridged One-Dimensional CdII Coordination Polymer

被引：3
|
作者：
Li, Li [1 ]
Liang, Jun [1 ]
Tian, Guangru [2 ]
机构：
[1] Ningxia Univ, Coll Chem & Chem Engn, Ningxia 750021, Peoples R China
[2] Shandong Univ, Dept Chem, Jinan 250100, Shandong, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期
关键词：
Thiocyanato-bridged; One-dimensional coordination polymer; Single crystal X-ray diffraction; COMPLEXES; CRYSTAL; CADMIUM(II); PHOSPHINE; GROWTH; CATION;
D O I：
10.1007/s10870-010-9834-3
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Synthesis and structure of a new thiocyanato-bridged one-dimensional coordination polymer, [Cd(NCS)(2)(TPPO)] (n) (1, TPPO = triphenylphosphine oxide), have been described. The title compound crystallizes in the monoclinic P2(1)/c space group with the unit cell parameters: a = 9.4917(4) , b = 22.2895(11) , c = 11.3300(5) , beta = 117.433(3)A degrees, V = 2127.49(17) (3), and Z = 4. The single crystal X-ray diffraction revealed that the structure of 1 features thiocyanate bridges and 1D zigzag chains. The chains consist of thiocyanato-bridged five-coordinated Cd atoms. And the coordination fashion of thiocyanate group is different from the previous reported five-coordinated Cd-NCS systems.
引用
收藏
页码：44 / 47
页数：4
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