Synthesis and Structure of a Thiocyanato-Bridged One-Dimensional CdII Coordination Polymer

被引：3

作者：

Li, Li ^{[1
]}

Liang, Jun ^{[1
]}

Tian, Guangru ^{[2
]}

机构：

[1] Ningxia Univ, Coll Chem & Chem Engn, Ningxia 750021, Peoples R China

[2] Shandong Univ, Dept Chem, Jinan 250100, Shandong, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期

关键词：

Thiocyanato-bridged; One-dimensional coordination polymer; Single crystal X-ray diffraction; COMPLEXES; CRYSTAL; CADMIUM(II); PHOSPHINE; GROWTH; CATION;

D O I：

10.1007/s10870-010-9834-3

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Synthesis and structure of a new thiocyanato-bridged one-dimensional coordination polymer, [Cd(NCS)(2)(TPPO)] (n) (1, TPPO = triphenylphosphine oxide), have been described. The title compound crystallizes in the monoclinic P2(1)/c space group with the unit cell parameters: a = 9.4917(4) , b = 22.2895(11) , c = 11.3300(5) , beta = 117.433(3)A degrees, V = 2127.49(17) (3), and Z = 4. The single crystal X-ray diffraction revealed that the structure of 1 features thiocyanate bridges and 1D zigzag chains. The chains consist of thiocyanato-bridged five-coordinated Cd atoms. And the coordination fashion of thiocyanate group is different from the previous reported five-coordinated Cd-NCS systems.

引用

页码：44 / 47

页数：4

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