Synthesis and Structure of a Thiocyanato-Bridged One-Dimensional CdII Coordination Polymer

被引：3
|
作者：
Li, Li [1 ]
Liang, Jun [1 ]
Tian, Guangru [2 ]
机构：
[1] Ningxia Univ, Coll Chem & Chem Engn, Ningxia 750021, Peoples R China
[2] Shandong Univ, Dept Chem, Jinan 250100, Shandong, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期
关键词：
Thiocyanato-bridged; One-dimensional coordination polymer; Single crystal X-ray diffraction; COMPLEXES; CRYSTAL; CADMIUM(II); PHOSPHINE; GROWTH; CATION;
D O I：
10.1007/s10870-010-9834-3
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Synthesis and structure of a new thiocyanato-bridged one-dimensional coordination polymer, [Cd(NCS)(2)(TPPO)] (n) (1, TPPO = triphenylphosphine oxide), have been described. The title compound crystallizes in the monoclinic P2(1)/c space group with the unit cell parameters: a = 9.4917(4) , b = 22.2895(11) , c = 11.3300(5) , beta = 117.433(3)A degrees, V = 2127.49(17) (3), and Z = 4. The single crystal X-ray diffraction revealed that the structure of 1 features thiocyanate bridges and 1D zigzag chains. The chains consist of thiocyanato-bridged five-coordinated Cd atoms. And the coordination fashion of thiocyanate group is different from the previous reported five-coordinated Cd-NCS systems.
引用
收藏
页码：44 / 47
页数：4
相关论文
共 50 条
  • [31] Hydrothermal synthesis, crystal structure and property of a one-dimensional Cu(II) coordination polymer
    Sun, Li Ping
    Niu, Shu Yun
    Jin, Jing
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2067 - U2067
  • [32] Synthesis and structure of 1-D heterometallic thiocyanato-bridged CuIIGdIII polymers with ferromagnetic properties
    Novitchi, G
    Costes, JP
    Donnadieu, B
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (09) : 1808 - 1812
  • [33] Spin Crossover in Bipyridine Derivative Bridged One-Dimensional Iron(III) Coordination Polymer
    Ishikawa, Ryuta
    Noda, Takeshi
    Ueno, Shunya
    Okubo, Takashi
    Yamakawa, Hirofumi
    Sakamoto, Ken-Ichi
    Kawata, Satoshi
    MAGNETOCHEMISTRY, 2020, 6 (03) : 1 - 14
  • [34] Biphase synthesis of a one-dimensional coordination polymer based on a dinuclear CdII secondary building unit and a novel semi-rigid dicarboxylate
    Zhang, Xiaolai
    Ying, Weiyong
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2012, 68 : M333 - U114
  • [35] Thiocyanato-bridged platinum heterocycles: structure and properties of disc-like metallomesogens
    Eran, BB
    Singer, D
    Pickardt, J
    Praefcke, K
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 620 (1-2) : 249 - 255
  • [36] A one-dimensional CdII coordination polymer:: catena-poly[cadmium(II)-bis(μ-6-methylpicolinato)]
    Kukovec, Boris-Marko
    Popovic, Zora
    Pavlovic, Gordana
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2007, 63 (09) : M389 - M391
  • [37] Synthesis and Crystal Structure of a Novel Polymeric Thiocyanato-Bridged Heteronuclear Complex of Copper(II) and Cadmium(II)
    Liang Shen
    Xuwen Feng
    Structural Chemistry, 2002, 13 : 437 - 441
  • [38] Synthesis and crystal structure of a novel polymeric thiocyanato-bridged heteronuclear complex of copper(II) and cadmium(II)
    Shen, L
    Feng, XW
    STRUCTURAL CHEMISTRY, 2002, 13 (5-6) : 437 - 441
  • [39] Synthesis and characterization of thiocyanato-bridged heteropolynuclear chromium(III)-copper(II) complexes
    Dobrzanska, L
    Wrzeszcz, G
    Grodzicki, A
    Rozploch, F
    POLISH JOURNAL OF CHEMISTRY, 2000, 74 (02) : 199 - 206
  • [40] Synthesis, crystal structure and luminescent properties of a thiocyanato-bridged two-dimensional heteronuclear polymeric complex of cadmium(II) and nickel(II)
    Bai, Yan
    Gao, Hui
    Dang, Dongbin
    Shang, Weili
    Pan, Xiao-jing
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 934 (1-3) : 53 - 56
12345