Synthesis and crystal structure of one-dimensional copper(II) coordination polymer bridged by pyrazine derivative

被引：4
|
作者：
Adachi, K
Sugiyama, Y
Kumagai, H
Inoue, K
Kitagawa, S
Kawata, S
机构：
[1] Shizuoka Univ, Dept Chem, Shizuoka 4228529, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 376卷
关键词：
coordination polymer; copper; pyrazine derivative;
D O I：
10.1080/10587250210797
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The one-dimensional copper(II) coordination polymers [Cu(tdpd)(pda)](n) (1) (H(2)tdpd = 1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile, pda = 1,2-phenylenediamine) has been synthesized and characterized. Compound I is a linear chain of copper(II) ions bridged by tdpd(2-) dianion with terminal pda ligand. Magnetic susceptibility measurement shows antiferromagnetic couplings between the copper(II) ions.
引用
收藏
页码：71 / 76
页数：6
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