Synthesis, crystal structure, magnetic properties and EPR studies of Cu/Hg bimetallic thiocyanato-bridged coordination polymer

被引：19
|
作者：
Kruszynski, Rafal [1 ]
Machura, Barbara [2 ]
Wolff, Mariusz [2 ]
Kusz, Joachim [3 ]
Mrozinski, Jerzy [4 ]
Bienko, Alina [4 ]
机构：
[1] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crystal Chem, PL-90924 Lodz, Poland
[2] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
[4] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 04期
关键词：
Coordination polymer; Heterometallic complexes; Magnetic properties; Copper and mercury; MOLECULAR-STRUCTURE; COMPLEXES; CHEMISTRY; CADMIUM; LIGANDS; SOLIDS;
D O I：
10.1016/j.ica.2008.05.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new Cu/Hg bimetallic thiocyanato-bridged coordination polymer, [Cu(2-bzpy)Hg(SCN)(4)](n), has been synthesized and characterized by elemental analysis, magnetic measurements, EPR, and X-ray crystallography. X-ray diffraction analysis reveals that the title complex structure creates 3D network. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1369 / 1373
页数：5
相关论文
共 50 条
  • [1] Synthesis, crystal structure, photoluminescent and antimicrobial properties of a thiocyanato-bridged copper(II) coordination polymer
    Chimaine, Feudjio Tsague
    Yufanyi, Divine Mbom
    Yuoh, Amah Colette Benedicta
    Eni, Donatus Bekindaka
    Agwara, Moise Ondoh
    COGENT CHEMISTRY, 2016, 2
  • [2] Heterobimetallic thiocyanato-bridged coordination polymers based on [Hg(SCN)4]2-:: Synthesis, crystal structure, magnetic properties and ESR studies
    Jian, Fang-Fang
    Xiao, Hai-Lian
    Liu, Fa Qian
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (12) : 3695 - 3703
  • [3] Synthesis and Structure of a Thiocyanato-Bridged One-Dimensional CdII Coordination Polymer
    Li Li
    Jun Liang
    Guangru Tian
    Journal of Chemical Crystallography, 2011, 41 : 44 - 47
  • [4] Synthesis and Structure of a Thiocyanato-Bridged One-Dimensional CdII Coordination Polymer
    Li, Li
    Liang, Jun
    Tian, Guangru
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (01) : 44 - 47
  • [5] Synthesis, structure and magnetic properties of two μ-oxo and thiocyanato-bridged manganese(II)-mercury(II) coordination polymers
    Li, Chun-Shang
    Xue, Lin
    Che, Yun-Xia
    Luo, Feng
    Zheng, Ji-Min
    Mak, Thomas C. W.
    INORGANICA CHIMICA ACTA, 2007, 360 (11) : 3569 - 3574
  • [6] A 2D thiocyanato-bridged copper(II)-manganese(II) bimetallic coordination polymer with ferromagnetic interactions
    Shi, JM
    Xu, W
    Zhao, B
    Cheng, P
    Liao, DZ
    Chen, XY
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (01) : 55 - 58
  • [7] Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties
    Bi, Jian-Hong
    Bi, Wen-Tao
    Hu, Nai-Liang
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (02) : 941 - 942
  • [8] Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer
    Krichen, Firas
    Walha, Siwar
    Kabadou, Ahlem
    CRYSTALLOGRAPHY REPORTS, 2017, 62 (07) : 1152 - 1156
  • [9] Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer
    Firas Krichen
    Siwar Walha
    Ahlem Kabadou
    Crystallography Reports, 2017, 62 : 1152 - 1156
  • [10] A new one-dimensional thiocyanato-bridged bimetallic compound [Cu(en)2Mn(NCS)4(H2O)2]n.: Synthesis, crystal structure, and magnetic properties
    Kou, HZ
    Liao, DZ
    Cheng, P
    Jiang, ZH
    Yan, SP
    Wang, GL
    Yao, XK
    Wang, HG
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1998, 76 (07): : 1102 - 1107
12345