Synthesis, crystal structure, magnetic properties and EPR studies of Cu/Hg bimetallic thiocyanato-bridged coordination polymer

被引：19
|
作者：
Kruszynski, Rafal [1 ]
Machura, Barbara [2 ]
Wolff, Mariusz [2 ]
Kusz, Joachim [3 ]
Mrozinski, Jerzy [4 ]
Bienko, Alina [4 ]
机构：
[1] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crystal Chem, PL-90924 Lodz, Poland
[2] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
[4] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 04期
关键词：
Coordination polymer; Heterometallic complexes; Magnetic properties; Copper and mercury; MOLECULAR-STRUCTURE; COMPLEXES; CHEMISTRY; CADMIUM; LIGANDS; SOLIDS;
D O I：
10.1016/j.ica.2008.05.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new Cu/Hg bimetallic thiocyanato-bridged coordination polymer, [Cu(2-bzpy)Hg(SCN)(4)](n), has been synthesized and characterized by elemental analysis, magnetic measurements, EPR, and X-ray crystallography. X-ray diffraction analysis reveals that the title complex structure creates 3D network. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1369 / 1373
页数：5
相关论文
共 50 条
  • [41] A three-dimensional heterometallic MnIICuII azide-bridged coordination polymer: Synthesis, structure, and magnetic properties
    Gu, Zhi-Guo
    Zhou, Wen
    Bao, Fei-Fei
    Pang, Chun-Yan
    Xu, Xin-Xin
    Li, Zaijun
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 22 : 22 - 25
  • [42] Synthesis, structure and magnetic properties of a novel 4,4′-azopyridine-bridged cobalt coordination polymer
    Zhu, LN
    Liang, M
    Wang, QL
    Wang, WZ
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Cheng, P
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 657 (1-3) : 157 - 163
  • [43] Synthesis, Crystal Structure, and Thermal, Magnetic and Spectroscopic Properties of New Thiocyanato Transition Metal Coordination Polymers Based on Pyrimidine as Ligand
    Wriedt, Mario
    Naether, Christian
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (3-4): : 569 - 575
  • [44] Synthesis, crystal structure, and DNA-binding studies of a one-dimensional copper(II) polymer bridged both by oxamidate and thiocyanato ligands
    Li, Yan-Tuan
    Liu, Zhi-Qiang
    Wu, Zhi-Yong
    Jiang, Man
    Li, Xiao-Wen
    STRUCTURAL CHEMISTRY, 2008, 19 (05) : 819 - 826
  • [45] Synthesis, crystal structure, and DNA-binding studies of a one-dimensional copper(II) polymer bridged both by oxamidate and thiocyanato ligands
    Yan-Tuan Li
    Zhi-Qiang Liu
    Zhi-Yong Wu
    Man Jiang
    Xiao-Wen Li
    Structural Chemistry, 2008, 19 : 819 - 826
  • [46] Synthesis and Magnetic Properties of Coordination Polymer of Cu(II)-Schiff Base
    Wang, Lin
    Bi, Jian-Hong
    Wang, Hong-Liang
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (02) : 937 - 938
  • [47] Dicarboxylate assisted synthesis of the monoclinic heterometallic tetrathiocyanato bridged copper(II) and mercury(II) coordination polymer {Cu[Hg(SCN)4])n: Synthesis, structural, vibration, luminescence, EPR studies and DFT calculations
    Khandar, Ali Akbar
    Klein, Axel
    Bakhtiari, Akbar
    Mahjoub, Ali Reza
    Pohl, Roland W. H.
    JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (02) : 379 - 386
  • [48] Synthesis, crystal structure and magnetism of 1D manganese(II) coordination polymer with thiocyanato as bridging ligand
    Shi, J-M.
    Chen, J-N.
    Liu, L-D.
    POLISH JOURNAL OF CHEMISTRY, 2006, 80 (11) : 1909 - 1913
  • [49] Synthesis and crystal structure of polymeric thiocyanato-bridged copper(II) complex with 4-nitro-2-[(2-piperidin-1ylethylimino)methyl] phenolate
    Z. X. Hang
    X. W. Wang
    B. Dong
    Russian Journal of Coordination Chemistry, 2012, 38 : 71 - 75
  • [50] Synthesis and crystal structure of polymeric thiocyanato-bridged copper(II) complex with 4-nitro-2-[(2-piperidin-1ylethylimino)methyl] phenolate
    Hang, Z. X.
    Wang, X. W.
    Dong, B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (01) : 71 - 75
12345