Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer

被引：0

作者：

Firas Krichen

Siwar Walha

Ahlem Kabadou

机构：

[1] Université de Sfax,Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences

来源：

Crystallography Reports | 2017年 / 62卷

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摘要：

A new mixed-valence coordination polymer [Cu3(SCN)4(DMSO)2]n (SCN– = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.

引用

页码：1152 / 1156

页数：4

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