Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer

被引：0
|
作者：
Firas Krichen
Siwar Walha
Ahlem Kabadou
机构：
[1] Université de Sfax,Laboratoire des Sciences des Matériaux et de l’Environnement, Faculté des Sciences
来源：
Crystallography Reports | 2017年 / 62卷
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new mixed-valence coordination polymer [Cu3(SCN)4(DMSO)2]n (SCN– = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.
引用
收藏
页码：1152 / 1156
页数：4
相关论文
共 50 条
  • [31] A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions
    Tao, J
    Zhang, Y
    Tong, ML
    Chen, XM
    Yuen, T
    Lin, CL
    Huang, XY
    Li, J
    [J]. CHEMICAL COMMUNICATIONS, 2002, (13) : 1342 - 1343
  • [32] MIXED-VALENCE COPPER(I)-COPPER(II) COMPOUNDS - ANALYSIS AND CLASSIFICATION OF CRYSTALLOGRAPHIC DATA
    DUNAJJURCO, M
    ONDREJOVIC, G
    MELNIK, M
    GARAJ, J
    [J]. COORDINATION CHEMISTRY REVIEWS, 1988, 83 : 1 - 28
  • [33] Hydrothermal syntheses and structures of two mixed-valence copper(I,II) 2-pyrazinecarboxylate coordination polymers
    Zhang, XM
    Fang, RQ
    [J]. INORGANIC CHEMISTRY, 2005, 44 (11) : 3955 - 3959
  • [34] Synthesis and spectral studies of mixed-valence binary copper(II)-copper(I) complexes
    Patel, RN
    Kumar, S
    Pandeya, KB
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (10): : 1104 - 1109
  • [35] CHARACTERIZATION OF A MIXED-VALENCE CYANO-BRIDGED COBALT(III)IRON(II) COMPLEX
    BAGGER, S
    STOLTZE, P
    [J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (03): : 247 - 250
  • [36] NITRITE COORDINATION TO COPPER(I), DICOPPER(I), AND MIXED-VALENCE CU(I)/CU(II) COMPLEXES - MODELING NITRITE BINDING TO COPPER SITES IN PROTEINS
    HALFEN, JA
    MAHAPATRA, S
    TOLMAN, WB
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 239 - INOR
  • [37] Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures
    Huang, XC
    Zhang, JP
    Lin, YY
    Yu, XL
    Chen, XM
    [J]. CHEMICAL COMMUNICATIONS, 2004, (09) : 1100 - 1101
  • [38] FORMAMIDE AS A PRECURSOR TO CYANIDE IN MIXED-VALENCE COPPER(I,II) CYANIDE COMPLEXES
    CONNOR, JA
    GIBSON, D
    PRICE, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02): : 347 - 350
  • [39] INTERACTION OF COPPER WITH HISTIDINE AND TIME-DEPENDENT FORMATION OF A MIXED-VALENCE CU(I)-CU(II) POLYMER
    WALKER, WR
    REEVES, RR
    LI, NC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 134 - 134
  • [40] A mixed-valence copper coordination polymer generated by a hydrothermal metal/ligand redox reaction process
    Wang, Xiu-Yan
    Wang, Jia-Jun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2008, 64 : M330 - M332
12345