Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

被引：141
|
作者：
Huang, XC
Zhang, JP
Lin, YY
Yu, XL
Chen, XM [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 09期
关键词：
D O I：
10.1039/b401691b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu-2(im)(3) and Cu-3(im)(4) (Him = imidazole), which are an unprecedented uninodal 4-connected 4.8(5) topological net and a 4-connected (4,4) net, respectively.
引用
收藏
页码：1100 / 1101
页数：2
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