A new mixed-valence copper(I,II) coordination polymer with 1-D chain structure

被引：17
|
作者：
Yu, Qing
Zhu, Li-Gang
Bian, He-Dong
Deng, Ji-Hua
Bao, Xiao-Ge
Liang, Hong [1 ]
机构：
[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guangxi 541004, Peoples R China
[2] Yulin Teachers Coll, Dept Chem & Chem Engn, Guangxi 537000, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 04期
基金：
中国国家自然科学基金;
关键词：
mixed valence; copper; coordination polymers; oxidation reactions; hydrothermal reactions;
D O I：
10.1016/j.inoche.2006.12.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mixed-valence copper(I,II) coordination polymer, {[(Cu2Cu2I2L4)-Cu-I-I-II] center dot 4DMF}(n) 1 (HL = N'-(2-methylene pyridine)ison-icotinohydrazide), was synthesized by N'-((N-oxide-pyridin-2-yl)methylene)isonicotinohydrazide and cuprous iodide. Complex I exhibit a one-dimensional structure built up from mixed valence units of (Cu2Cu2L4)-Cu-I-L-II linked by iodide anions. The coordinated environments of Cu(II) and Cu(I) are distorted octahedron and tetrahedron, respectively. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：437 / 439
页数：3
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