One-pot synthesis of aniline derivatives from nitroarenes under mild conditions promoted by a recyclable polymer-supported palladium catalyst

被引：54

作者：

Dell'Anna, Maria Michela ^{[1
]}

Mastrorilli, Piero ^{[1
]}

Rizzuti, Antonino ^{[1
]}

Leonelli, Cristina ^{[2
]}

机构：

[1] Politecn Bari, Dipartimento Ingn Acque & Chim, I-70125 Bari, Italy

[2] Univ Modena & Reggio Emilia, Dipartimento Ingn Mat & Ambiente, I-41125 Modena, Italy

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 401卷 / 1-2期

关键词：

One-pot reductive amination; Palladium nanoparticles; Supported catalysis; TEM; DIRECT REDUCTIVE AMINATION; SECONDARY-AMINES; NITRO ARYLS; ALDEHYDES; NANOPARTICLES; EFFICIENT; KETONES; ALKYLATION; COMPLEX; MONOALKYLATION;

D O I：

10.1016/j.apcata.2011.05.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work describes the one-pot direct reductive amination of carbonyl compounds with nitroarenes promoted by a polymer supported palladium catalyst, in the presence of molecular hydrogen as the reductant. This methodology is applicable, with slight differences, to both aliphatic and aromatic aldehydes. The operational simplicity, the mild reaction conditions, the high yields and the good recyclability of the supported catalyst are major advantages of this method. TEM observations of the catalyst showed that the active species are palladium nanoparticles having a size distribution centered at 5 nm within the polymeric support. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：134 / 140

页数：7

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