Formation of [NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- via CS2 Insertion into Nickel(III) Hydride Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]-

被引：15
|
作者：
Lai, Kuan-Ting [1 ]
Ho, Wei-Chieh [1 ]
Chiou, Tzung-Wen [1 ]
Liaw, Wen-Feng [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 08期
关键词：
VULGARIS MIYAZAKI-F; NIFE HYDROGENASE; ACTIVE-SITE; MONONUCLEAR NICKEL(III); DESULFOVIBRIO-GIGAS; RALSTONIA-EUTROPHA; CARBON-DISULFIDE; COMPLEXES; RELEVANCE; ACTIVATION;
D O I：
10.1021/ic400293k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Insertion of CS2 into the thermally unstable nickel(111) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)(3))] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)(3)] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OC-Me2CMe2O) in tetrahydrofuran at -80 degrees C via a metathesis reaction, readily affords [PPN][Ni-III(kappa(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)(3))] (2) featuring a kappa(1)-S2CH moiety.
引用
收藏
页码：4151 / 4153
页数：3
相关论文
共 50 条
  • [31] Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O
    Vorobieva, S. N.
    Baidina, I. A.
    Belyaev, A. V.
    Korolkov, I. V.
    Alferova, N. I.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (08) : 1606 - 1612
  • [32] Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O
    S. N. Vorobieva
    I. A. Baidina
    A. V. Belyaev
    I. V. Korolkov
    N. I. Alferova
    Journal of Structural Chemistry, 2015, 56 : 1606 - 1612
  • [33] Crystal structure and spectroscopic studies of [2,6-(C2H5)2C6H3NH3]2H3P3O10
    Smirani, W.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (08) : 1727 - 1737
  • [34] COMPRESSIBILITIES AND ISOCHORES OF (C3F7COOCH2)4C, C-SI4O4(CH3)8, N-C5H12,N-C8H18, 2,2,4-C5H9(CH3)3, C-C5H10, C-C6H12, C-C6H11CH3, C6H5CH3, P-C6H4(CH3)2, S-C6H3(CH3)3, CH2CL2
    SHINODA, K
    HILDEBRAND, JH
    JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (01): : 183 - &
  • [35] Alkali-metal isocyanurate Cs3(H2C3N3O3)3(H3C3N3O3)•3H2O: synthesis and characterization
    Wang, Xinyue
    Wang, Dandan
    Liu, Yujie
    Wang, Jinhui
    CRYSTENGCOMM, 2024, 26 (29) : 3948 - 3953
  • [36] Computational study of the mechanism and product yields in the reaction systems C2H3+CH3 ⇆ C3H6 ⇆ H+C3H5 and C2H3+CH3 → CH4+C2H2
    Stoliarov, SI
    Knyazev, VD
    Slagle, IR
    JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (30): : 6952 - 6966
  • [37] Synthesis and characterization of oxorhenium(V)-'3+1' mixed thiolate [SNS]/[S] and [ONS]/[S] complexes.: Crystal and molecular structures of [ReO(η 3-SCH2C5H3NCH2S)(η1-C6H4Br-4-S)], [ReO(η3-SCH2C5H3NCH2O)(η1-C6H4X-4-S)] (X = Cl, OMe), [ReO(η3-SCH2C5H3NCH2O)(η1-C6H4OCH3-4-CH2S)] and [ReO(η3-SCH2C5H3NCH2S)(η1-C5H4NH-2-S)][Cl]
    Chen, XY
    Femia, FJ
    Babich, JW
    Zubieta, J
    INORGANICA CHIMICA ACTA, 2000, 307 (1-2) : 88 - 96
  • [38] Synthesis and crystal structure of [3,5-(CH3)2C6H3NH3]4P4O12.3H2O
    Aloui, Z
    Abid, S
    Rzaigui, M
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (05) : 923 - 926
  • [39] SYNTHESIS AND CRYSTAL STRUCTURE OF Mo3（μ3-O）(μ-S)3[S2P（OEt）2]4（C3H3N2）
    Huang Mingdong Lu Shaofan Huang Jianquan Huang JinlingFujian Institiute of Research on the Structure of Matter
    结构化学, 1987, (01) : 29 - 33
  • [40] On the reactivity of C3O2 with [C3H6]+
    Pandolfo, L.
    Somogyi, A.
    Catinella, S.
    Traldi, P.
    Journal of Mass Spectrometry, 1995, 30 (07):
12345