SYNTHESIS AND CRYSTAL STRUCTURE OF Mo3（μ3-O）(μ-S)3[S2P（OEt）2]4（C3H3N2）

被引：0

作者：

Huang Mingdong Lu Shaofan Huang Jianquan Huang JinlingFujian Institiute of Research on the Structure of Matter

机构：

来源：

Chinese Journal of Structural Chemistry | 1987年 / 01期

关键词：

一彻; Mo; C3H3N2; OEt; SYNTHESIS AND CRYSTAL STRUCTURE OF Mo3; S2P;

D O I：

10.14102/j.cnki.0254-5861.1987.01.007

中图分类号：

学科分类号：

摘要：

Mr=1164, space group C2/c, a=14.954(13)A,b=22.323(6)A,c=27.003(18)A,β=98.23(7)°,V=8920 A3, Z=8. Final R=0.069 for 2818 unique diffraction data with I≥30(I). The title cluster compound is of Ml configuration with a triple bridging atom O and with a ’loosely coordinated site’ occupied by an imidazole ligand. Three Mo-Mo bond lengths are 2.657 (2), 2.649(2),and 2.646(2)A,respectively. The average bond length of Mo-(μ3-O) bonds is 2.052 A.

引用

页码：29 / 33

页数：5

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