CRYSTAL STRUCTURE OF Mo3（μ3-S）(μ-S)2[S2P（OEt）2]3][SOP（OEt）2]（0）2

被引：0

作者：

Lu Shaofang Huang Jianquan Huang Jinling Lu JiaxiFujian Institute of Research on the Structure of Matter

机构：

来源：

Chinese Journal of Structural Chemistry | 1984年 / 02期

关键词：

Mo; S2P; OEt; CRYSTAL STRUCTURE OF Mo3; SOP;

D O I：

10.14102/j.cnki.0254-5861.1984.02.017

中图分类号：

学科分类号：

摘要：

M=1140.85, monoclinic, P21/c. a=12.748(2), b=14.320(2), c=23.118 (3)A,β=101.07(1)°, V=4141(2)A3, Z=4, Dc=1.830 g.cm-3. Final R=0.039 for 4160 reflections.The title compound is a rather irregular trinuclear molybdenum cluster having only two M-M bonds with two shorter Mo-Mo distances of 2.808(1), 2.839(1), and one longer Mo-Mo distance of 3.337(1)8. The existence of two Mo-Mo bonds is coincident with the electron counting for {Mo3} cluster core, and may be regarded as a result of the oxidation of a compound Mo3(μ3-S)(μ-S)2 (μ-L)[S2P(OEt)2]4(L’) (L’=neutral ligands)1 characterized by us previously.

引用

页码：151 / 154

页数：4

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