Synthesis and crystal structure of [3,5-(CH3)2C6H3NH3]4P4O12.3H2O

被引：4
|
作者：
Aloui, Z [1 ]
Abid, S [1 ]
Rzaigui, M [1 ]
机构：
[1] Fac Sci, Lab Chim Mat, Zarzouna 7021, Bizerte, Tunisia
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2004年 / 65卷 / 05期
关键词：
chemical synthesis; x-ray diffraction; infrared spectroscopy; thermogravimetric analysis; crystal structure;
D O I：
10.1016/j.jpcs.2003.10.049
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemical preparation and crystal structure are given for a new cyclotetraphosphate: [3,5-(CH3)(2)C6H3NH3](4)P4O12.3H(2)O. This compound is triclinic P1 with the following unit-cell parameters: a = 8.298(3), b = 8.299(3), c = 17.242(7)Angstrom, alpha = 97.13(3), beta = 102.72(3), gamma = 64.55(3)degrees, Z = 1 and V = 1045.2(8)Angstrom(3). The crystal structure has been solved and refined to R = 0.040 using 6086 independent reflections. The atomic arrangement can be described as layers organization. Layers built by P4O12 ring anions, ammonium groups and water molecules parallel to the plan (001), between which the organic groups are located. Characterization by X-ray diffraction, IR absorption, and thermal analysis are described. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：923 / 926
页数：4
相关论文
共 50 条
  • [1] Synthesis and crystal structure of [3,5-(CH3O)2C6H3NH3]4P4O12•4H2O
    Aloui, Z
    Abid, S
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2002, 37 (04) : 697 - 703
  • [2] Crystal structure and characterization of [2,5-(CH3O)2C6H3NH3]4P4O12•2H2O
    Aloui, Z
    Abid, S
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2005, 40 (12) : 2056 - 2063
  • [3] Synthesis and characterization of a new organic dihydrogenornonophosphate [3,5-(CH3O)2C6H3NH3]2(H2PO4)2
    Kaabi, K
    Ben Nasr, C
    Lefebvre, F
    MATERIALS RESEARCH BULLETIN, 2004, 39 (02) : 205 - 215
  • [4] Synthesis and characterization of a new monophosphate [2,5-(CH3)2C6H3NH3]H2PO4
    Kaabi, K
    Ben Nasr, C
    Rzaigui, M
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (11) : 1759 - 1764
  • [5] Crystal structure of 3,4-dimethylanilinium dihydrogenmonophosphate, [(CH3)2C6H3NH3]H2PO4
    Smirani, W
    Rzaigui, M
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (03): : 263 - 264
  • [6] Synthesis and crystal structure of to (o-CH3C6H4NH3)2H2P2O7
    Akriche, S
    Rzaigui, M
    SOLID STATE SCIENCES, 2000, 2 (03) : 397 - 403
  • [7] Structural and physicochemical studies of [2,3-(CH3)2C6H3NH3]4HP3O10.2H2O
    Souissi, S.
    Smirani, W.
    Ben Nasr, C.
    Rzaigui, M.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (11) : 2731 - 2743
  • [8] Synthesis and crystal structures of a new (2,3-(CH3)2C6H3NH3)H2XO4 (X = P, As)
    Rayes, A
    Ben Nasr, C
    Rzaigui, A
    MATERIALS RESEARCH BULLETIN, 2004, 39 (7-8) : 1113 - 1121
  • [9] Synthesis and characterization of a new organic sulphate, [2,3-(CH3)2C6H3NH3]HSO4•H2O
    Sahbani, T.
    Smirani, W.
    Al-Deyab, Salem S.
    Rzaigui, M.
    MATERIALS RESEARCH BULLETIN, 2012, 47 (06) : 1455 - 1458
  • [10] CRYSTAL-STRUCTURE OF NALI[NH3-(CH2)2-NH3]P4O12.3H2O
    BDIRI, M
    JOUINI, A
    JOURNAL OF SOLID STATE CHEMISTRY, 1989, 83 (02) : 350 - 360
12345