Formation of [NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- via CS2 Insertion into Nickel(III) Hydride Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]-

被引：15

作者：

Lai, Kuan-Ting ^{[1
]}

Ho, Wei-Chieh ^{[1
]}

Chiou, Tzung-Wen ^{[1
]}

Liaw, Wen-Feng ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 08期

关键词：

VULGARIS MIYAZAKI-F; NIFE HYDROGENASE; ACTIVE-SITE; MONONUCLEAR NICKEL(III); DESULFOVIBRIO-GIGAS; RALSTONIA-EUTROPHA; CARBON-DISULFIDE; COMPLEXES; RELEVANCE; ACTIVATION;

D O I：

10.1021/ic400293k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of CS2 into the thermally unstable nickel(111) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)(3))] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)(3)] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OC-Me2CMe2O) in tetrahydrofuran at -80 degrees C via a metathesis reaction, readily affords [PPN][Ni-III(kappa(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)(3))] (2) featuring a kappa(1)-S2CH moiety.

引用

页码：4151 / 4153

页数：3

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