PdCl2(1-methylimidazole)2-catalysed Suzuki-Miyaura and Mizoroki-Heck reactions performed in neat water

被引：2
|
作者：
Li, Yao [1 ]
Lin, Xiao-Fang [1 ]
Liu, Meng-Yuan [1 ]
Zhang, Lu-Lu [1 ]
Jin, Ai-Ping [1 ]
Lu, Jian-Mei [1 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2013年 / 05期
基金：
中国国家自然科学基金;
关键词：
palladium complex; Suzuki-Miyaura coupling; Mizoroki-Heck coupling; water as solvent; green chemistry; CROSS-COUPLING REACTIONS; PALLADIUM(II) COMPLEXES; LIGAND-FREE; ARYL; ARYLATION; CATALYSTS; ACIDS;
D O I：
10.3184/174751913X13662179283121
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PdCl2(1-methylimidazole)(2) was an effective catalyst in neat water for the Suzuki-Miyaura and Mizoroki-Heck reactions of aryl bromides and iodides with, respectively, arylboronic acids and acrylic acid. Under optimal conditions, the products, variously substituted biphenyls and monosubstituted trans-cinnamic acids, respectively, were formed in good to almost quantitative yields.
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页码：294 / 297
页数：4
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