PdCl2(1-methylimidazole)2-catalysed Suzuki-Miyaura and Mizoroki-Heck reactions performed in neat water

被引：2
|
作者：
Li, Yao [1 ]
Lin, Xiao-Fang [1 ]
Liu, Meng-Yuan [1 ]
Zhang, Lu-Lu [1 ]
Jin, Ai-Ping [1 ]
Lu, Jian-Mei [1 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2013年 / 05期
基金：
中国国家自然科学基金;
关键词：
palladium complex; Suzuki-Miyaura coupling; Mizoroki-Heck coupling; water as solvent; green chemistry; CROSS-COUPLING REACTIONS; PALLADIUM(II) COMPLEXES; LIGAND-FREE; ARYL; ARYLATION; CATALYSTS; ACIDS;
D O I：
10.3184/174751913X13662179283121
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PdCl2(1-methylimidazole)(2) was an effective catalyst in neat water for the Suzuki-Miyaura and Mizoroki-Heck reactions of aryl bromides and iodides with, respectively, arylboronic acids and acrylic acid. Under optimal conditions, the products, variously substituted biphenyls and monosubstituted trans-cinnamic acids, respectively, were formed in good to almost quantitative yields.
引用
收藏
页码：294 / 297
页数：4
相关论文
共 50 条
  • [21] Efficient imidazolium salts for palladium-catalyzed Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions
    Amini, Mojtaba
    Bagherzadeh, Mojtaba
    Rostamnia, Sadegh
    CHINESE CHEMICAL LETTERS, 2013, 24 (05) : 433 - 436
  • [22] Palladium nanoparticles supported on silicadiphenyl phosphinite (SDPP) as efficient catalyst for Mizoroki-Heck and Suzuki-Miyaura coupling reactions
    Iranpoor, Nasser
    Firouzabadi, Habib
    Motevalli, Somayeh
    Talebi, Mohsen
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 708 : 118 - 124
  • [23] Pd(II) complexes of Schiff bases and their application as catalysts in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions
    Keles, Mustafa
    Keles, Hulya
    Emir, Duygu Melis
    APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (08) : 543 - 548
  • [24] Palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura reactions using naphthalenomethyl-substituted imidazolidin-2-ylidene ligands in aqueous media
    Aktas, Aydin
    Akkoc, Senem
    Gok, Yetkin
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (16) : 2901 - 2909
  • [25] PdCl2 Immobilized in Polyacrylamide: a Low Cost and Eco-Friendly Catalyst for Suzuki-Miyaura Reactions
    Alvarenga, Glademir
    Ruas, Caroline P.
    Vicenti, Juliano R. M.
    Duarte, Fabio A.
    Gelesky, Marcos A.
    Rosa, Gilber R.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2016, 27 (04) : 787 - 793
  • [26] Ferrocenylimine Palladium (II) Complexes: Synthesis, Characterization and Application in Mizoroki-Heck and Suzuki-Miyaura Cross-Coupling Reactions
    Matsheku, Asanda C.
    Tia, Richard
    Maumela, Munaka C.
    Makhubela, Banothile C. E.
    CATALYSTS, 2021, 11 (07)
  • [27] Pd- and Ni-Pyridyl Complexes Deposited as Films for Suzuki-Miyaura and Mizoroki-Heck Cross Coupling Reactions
    Zhao, Xiuhua
    Zhang, Jie
    Zhao, Yayun
    Li, Xing
    CATALYSIS LETTERS, 2015, 145 (12) : 2010 - 2019
  • [28] A PdCl2-ionic liquid brush assembly: an efficient and reusable catalyst for Mizoroki-Heck reaction in neat water
    Shi, Xianying
    Han, Xiaoyan
    Ma, Wenjuan
    Fan, Juan
    Wei, Junfa
    APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (01) : 16 - 20
  • [29] Polyaniline-anchored palladium catalyst-mediated Mizoroki-Heck and Suzuki-Miyaura reactions and one-pot Wittig-Heck and Wittig-Suzuki reactions
    Patel, Heta A.
    Patel, Arun L.
    Bedekar, Ashutosh V.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (01) : 1 - 6
  • [30] A new thioglycolic ester β-cyclodextrin/PdCl2 in water: An accessible catalyst for the Suzuki-Miyaura coupling reaction
    de Souza, Viviane Costa
    Ramos, Gabriel dos Santos
    Leite, Juliana Lago
    dos Santos, Mauricio Brandao
    Otubo, Larissa
    Camargo, Zaine Teixeira
    Victor, Mauricio Moraes
    CARBOHYDRATE POLYMERS, 2023, 301
12345