PdCl2(1-methylimidazole)2-catalysed Suzuki-Miyaura and Mizoroki-Heck reactions performed in neat water

被引：2
|
作者：
Li, Yao [1 ]
Lin, Xiao-Fang [1 ]
Liu, Meng-Yuan [1 ]
Zhang, Lu-Lu [1 ]
Jin, Ai-Ping [1 ]
Lu, Jian-Mei [1 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2013年 / 05期
基金：
中国国家自然科学基金;
关键词：
palladium complex; Suzuki-Miyaura coupling; Mizoroki-Heck coupling; water as solvent; green chemistry; CROSS-COUPLING REACTIONS; PALLADIUM(II) COMPLEXES; LIGAND-FREE; ARYL; ARYLATION; CATALYSTS; ACIDS;
D O I：
10.3184/174751913X13662179283121
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
PdCl2(1-methylimidazole)(2) was an effective catalyst in neat water for the Suzuki-Miyaura and Mizoroki-Heck reactions of aryl bromides and iodides with, respectively, arylboronic acids and acrylic acid. Under optimal conditions, the products, variously substituted biphenyls and monosubstituted trans-cinnamic acids, respectively, were formed in good to almost quantitative yields.
引用
收藏
页码：294 / 297
页数：4
相关论文
共 50 条
  • [31] Synthesis, characterization, Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions of Schiff base-Pd(II) complexes
    Akdeniz, Abbas
    Turan, Nevin
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1287
  • [32] Pd(OAc)2/[C18-DABCO-C18]2Br: a nano palladium catalytic approach for Mizoroki-Heck and Suzuki-Miyaura coupling reactions in water
    Rajmane, Archana
    Pawara, Chunilal
    Kamble, Sumit
    More, Utkarsh
    Patil, Suresh
    Kumbhar, Arjun
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (43) : 20171 - 20181
  • [33] The Palladium Slow-Release Pre-Catalysts and Nanoparticles in the "Phosphine-Free" Mizoroki-Heck and Suzuki-Miyaura Reactions
    Sigeev, Alexander S.
    Peregudov, Alexander S.
    Cheprakov, Andrei V.
    Beletskaya, Irina P.
    ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (2-3) : 417 - 429
  • [34] Magnetic dendritic polymer nanocomposites as supports for palladium: a highly efficient and reusable catalyst for Mizoroki-Heck and Suzuki-Miyaura coupling reactions
    Ma, Rong
    Yang, Pengbo
    Bian, Fengling
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (06) : 4748 - 4756
  • [35] A highly active palladium(II)-bis(oxazoline) catalyst for Suzuki-Miyaura, Mizoroki-Heck and sonogashira coupling reactions in aqueous dimethylformamide
    Ibrahim, Mansur B.
    El Ali, Bassam
    Fettouhi, Mohammed
    Ouahab, Lahcene
    APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (06) : 400 - 407
  • [36] Pd Nanoparticles Decorated on Jute Sticks: Dip-Catalyst of Suzuki-Miyaura and Mizoroki-Heck C-C Bond Formation Reactions in Water
    Kalanthoden, Abdul Nasar
    Shaikh, M. Nasiruzzaman
    Aziz, Md Abdul
    Rani, S. Kutti
    CHEMISTRYSELECT, 2019, 4 (44): : 12832 - 12840
  • [37] Palladium supported on silica-chitosan hybrid material (Pd-CS@SiO2) for Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions
    Jadhav, Sanjay
    Kumbhar, Arjun
    Salunkhe, Rajashri
    APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (06) : 339 - 345
  • [38] Magnetic apple seed starch functionalized with 2,2′-furil as a green host for cobalt nanoparticles: Highly active and reusable catalyst for Mizoroki-Heck and the Suzuki-Miyaura reactions
    Arghan, Maryam
    Koukabi, Nadiya
    Kolvari, Eskandar
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (09)
  • [39] Highly efficient polymer-stabilized palladium heterogeneous catalyst: Synthesis, characterization and application for Suzuki-Miyaura and Mizoroki-Heck coupling reactions
    Targhan, Homa
    Hassanpour, Alireza
    Bahrami, Kiumars
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (10)
  • [40] Highly Active Heterogeneous PdCl2/MOF Catalyst for Suzuki-Miyaura Cross-Coupling Reactions of Aryl Chloride
    Gong, Xue-Fang
    Zhang, Ling-Yan
    Zhang, Hui-Xin
    Cui, Yu-Meng
    Jin, Fen-Chun
    Liu, Yu
    Zhai, Yu-Feng
    Li, Jin-Heng
    Liu, Gui-Yan
    Zeng, Yong-Fei
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (15): : 1336 - 1341
12345