Suzuki-Miyaura, Mizoroki-Heck carbon-carbon coupling and hydrogenation reactions catalysed by PdII and RhI complexes containing cyclodiphosphazane cis-{tBuNP(OC6H4OMe-o)}2

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作者：
Sasmita Mohanty
Maravanji S. Balakrishna
机构：
[1] Indian Institute of Technology Bombay,Phosphorus Laboratory, Department of Chemistry
来源：
Journal of Chemical Sciences | 2010年 / 122卷
关键词：
Cyclodiphosphazane; catalysis; palladium and rhodium complexes; Suzuki-Miyaura reactions; Mizoroki-Heck reactions; hydrogenation reactions;
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摘要：
The catalytic activity of the palladium complex cis-[PdCl2{(tBuNP(OC6H4OMe-o))2-κP}2] (2) containing cis-{tBuNP(OC6H4OMe-o)}2 (1) in Suzuki-Miyaura and Mizoroki-Heck carbon-carbon cross coupling reactions is described. The compound 2 also displays very high activity in Mizoroki-Heck coupling reactions. The rhodium(I) complex [RhCl(COD){(tBuNP(OC6H4OMe-o))2-κP}] (3) acts as an excellent catalyst for the hydrogenation of several terminal olefins.
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页码：137 / 142
页数：5
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