A highly porous agw-type metal-organic framework and its CO2 and H2 adsorption capacity

被引：36
|
作者：
Lu, Zhiyong [1 ]
Du, Liting [1 ]
Zheng, Baishu [2 ]
Bai, Junfeng [1 ]
Zhang, Mingxing [1 ]
Yun, Ruirui [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Theoret Chem & Mol Simulat, Xiangtan 411201, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 45期
关键词：
SURFACE-AREA; HYDROGEN STORAGE; CARBON-DIOXIDE; GAS-STORAGE; CAPTURE; POROSITY; SORPTION; BINDING; SITES;
D O I：
10.1039/c3ce41119b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal-organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m(2) g(-1), a large capacity of CO2 (21.2 mmol g(-1) at 298 K and 20 bar) and a good H-2 adsorption (5.8 wt% at 77 K and 20 bar).
引用
收藏
页码：9348 / 9351
页数：4
相关论文
共 50 条
  • [1] Highly selective CO2 capture of an agw-type metal-organic framework with inserted amides: experimental and theoretical studies
    Duan, Jingui
    Yang, Zhen
    Bai, Junfeng
    Zheng, Baishu
    Li, Yizhi
    Li, Shuhua
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (25) : 3058 - 3060
  • [2] High Gas Adsorption Capacity of an agw-Type Metal-Organic Framework Decorated with Methyl Groups
    Du, Liting
    Lu, Zhiyong
    Xu, Li
    Ma, Mengtao
    Zhang, Jinchi
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (29) : 4727 - 4730
  • [3] A Microporous Copper Metal-Organic Framework with High H2 and CO2 Adsorption Capacity at Ambient Pressure
    Laessig, Daniel
    Lincke, Joerg
    Moellmer, Jens
    Reichenbach, Christian
    Moeller, Andreas
    Glaeser, Roger
    Kalies, Grit
    Cychosz, Katie A.
    Thommes, Matthias
    Staudt, Reiner
    Krautscheid, Harald
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (44) : 10344 - 10348
  • [4] Rational Design and Synthesis of a Highly Porous Copper-Based Interpenetrated Metal-Organic Framework for High CO2 and H2 Adsorption
    Bose, Purnandhu
    Bai, Linyi
    Ganguly, Rakhesh
    Zou, Ruqiang
    Zhao, Yanli
    [J]. CHEMPLUSCHEM, 2015, 80 (08): : 1259 - +
  • [5] Design and Synthesis of Two Porous Metal-Organic Frameworks with nbo and agw Topologies Showing High CO2 Adsorption Capacity
    Liang, Zhiqiang
    Du, Jingjing
    Sun, Libo
    Xu, Jin
    Mu, Ying
    Li, Yi
    Yu, Jihong
    Xu, Ruren
    [J]. INORGANIC CHEMISTRY, 2013, 52 (19) : 10720 - 10722
  • [6] Highly Porous Ionic rht Metal-Organic Framework for H2 and CO2 Storage and Separation: A Molecular Simulation Study
    Babarao, R.
    Eddaoudi, M.
    Jiang, J. W.
    [J]. LANGMUIR, 2010, 26 (13) : 11196 - 11203
  • [7] Highly efficient H2/CO2 separation via an ultrathin metal-organic framework membrane
    Hou, Jiamin
    Wei, Yanying
    Zhou, Sheng
    Wang, Yanjie
    Wang, Haihui
    [J]. CHEMICAL ENGINEERING SCIENCE, 2018, 182 : 180 - 188
  • [8] High H2 and CH4 Adsorption Capacity of a Highly Porous (2,3,4)-Connected Metal-Organic Framework
    Lu, Zhiyong
    Du, Liting
    Tang, Kuanzhen
    Bai, Junfeng
    [J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (06) : 2252 - 2255
  • [9] Structural basis of CO2 adsorption in a porous metal-organic framework material
    Allen, Andrew J.
    Wong-Ng, Winnie
    Cockayne, Eric
    Culp, Jeffrey T.
    Matranga, Christopher
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2019, 75 : A336 - A337
  • [10] Fluorinated Metal-Organic Frameworks: Advantageous for Higher H2 and CO2 Adsorption or Not?
    Pachfule, Pradip
    Chen, Yifei
    Jiang, Jianwen
    Banerjee, Rahul
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (02) : 688 - 694
12345