A highly porous agw-type metal-organic framework and its CO2 and H2 adsorption capacity

被引：36
|
作者：
Lu, Zhiyong [1 ]
Du, Liting [1 ]
Zheng, Baishu [2 ]
Bai, Junfeng [1 ]
Zhang, Mingxing [1 ]
Yun, Ruirui [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Theoret Chem & Mol Simulat, Xiangtan 411201, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 45期
关键词：
SURFACE-AREA; HYDROGEN STORAGE; CARBON-DIOXIDE; GAS-STORAGE; CAPTURE; POROSITY; SORPTION; BINDING; SITES;
D O I：
10.1039/c3ce41119b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal-organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m(2) g(-1), a large capacity of CO2 (21.2 mmol g(-1) at 298 K and 20 bar) and a good H-2 adsorption (5.8 wt% at 77 K and 20 bar).
引用
收藏
页码：9348 / 9351
页数：4
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