A highly porous agw-type metal-organic framework and its CO2 and H2 adsorption capacity

被引：38
|
作者：
Lu, Zhiyong [1 ]
Du, Liting [1 ]
Zheng, Baishu [2 ]
Bai, Junfeng [1 ]
Zhang, Mingxing [1 ]
Yun, Ruirui [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Theoret Chem & Mol Simulat, Xiangtan 411201, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 45期
关键词：
SURFACE-AREA; HYDROGEN STORAGE; CARBON-DIOXIDE; GAS-STORAGE; CAPTURE; POROSITY; SORPTION; BINDING; SITES;
D O I：
10.1039/c3ce41119b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unsymmetrical tricarboxylate ligand with linking alkyne moiety has been used to construct a highly porous metal-organic framework with agw topology. The obtained Cu(II) MOF exhibits a high BET surface area of 3337.0 m(2) g(-1), a large capacity of CO2 (21.2 mmol g(-1) at 298 K and 20 bar) and a good H-2 adsorption (5.8 wt% at 77 K and 20 bar).
引用
收藏
页码：9348 / 9351
页数：4
相关论文
共 50 条
  • [31] Metal-organic framework materials designed for enhanced CO2 adsorption
    Doonan, Christian J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [32] Synthesis of highly hydrophobic and permselective metal-organic framework Zn(BDC)(TED)0.5 membranes for H2/CO2 separation
    Huang, Aisheng
    Chen, Yifei
    Liu, Qian
    Wang, Nanyi
    Jiang, Jianwen
    Caro, Juergen
    JOURNAL OF MEMBRANE SCIENCE, 2014, 454 : 126 - 132
  • [33] Effects of metal-organic framework properties on CO2/H2 separation performance for pre-combustion CO2 capture via pressure swing adsorption
    Herm, Zoey
    Swisher, Joseph A.
    Smit, Berend
    Krishna, Rajamani
    Long, Jeffrey R.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [34] CO2 Adsorption in Metal-organic Frameworks
    Kim, Jun
    Kim, Hee-Young
    Ahn, Wha-Seung
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2013, 51 (02): : 171 - 180
  • [35] Adsorption and diffusion of H2, N2, CO, CH4 and CO2 in UTSA-16 metal-organic framework extrudates
    Agueda, Vicente I.
    Delgado, Jose A.
    Uguina, Maria A.
    Brea, Pablo
    Spjelkavik, Aud I.
    Blom, Richard
    Grande, Carlos
    CHEMICAL ENGINEERING SCIENCE, 2015, 124 : 159 - 169
  • [36] Efficient electrochemical synthesis of a manganese-based metal-organic framework for H2 and CO2 uptake
    Asghar, Aisha
    Iqbal, Naseem
    Noor, Tayyaba
    Kariuki, Benson M.
    Kidwell, Luke
    Easun, Timothy L.
    GREEN CHEMISTRY, 2021, 23 (03) : 1220 - 1227
  • [37] Flexible Soft-Solid Metal-Organic Framework Composite Membranes for H2/CO2 Separation
    Shu, Lun
    Peng, Yuan
    Yao, Rui
    Song, Hongling
    Zhu, Chenyu
    Yang, Weishen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (14)
  • [38] An ato-topology metal-organic framework with large C2H2 adsorption and C2H2/CO2 separation capacity
    Wang, Ting
    Jiang, Zhi-Jie
    Wang, Ying
    Wei, Rong-Jia
    Zeng, Heng
    Lu, Weigang
    Li, Dan
    DALTON TRANSACTIONS, 2022, 51 (44) : 16800 - 16804
  • [39] Porous Metal-Organic Polyhedral Framework containing Cuboctahedron Cages as SBUs with High Affinity for H2 and CO2 Sorption: A Heterogeneous Catalyst for Chemical Fixation of CO2
    Maity, Kartik
    Karan, Chandan Kumar
    Biradha, Kumar
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (43) : 10988 - 10993
  • [40] Porous NbO-type metal-organic framework with inserted acylamide groups exhibiting highly selective CO2 capture
    Zheng, Baishu
    Liu, Heting
    Wang, Zhaoxu
    Yu, Xianyong
    Yi, Pinggui
    Bai, Junfeng
    CRYSTENGCOMM, 2013, 15 (18): : 3517 - 3520
12345