High H2 and CH4 Adsorption Capacity of a Highly Porous (2,3,4)-Connected Metal-Organic Framework

被引：38
|
作者：
Lu, Zhiyong [1 ]
Du, Liting [1 ]
Tang, Kuanzhen [1 ]
Bai, Junfeng [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2013年 / 13卷 / 06期
关键词：
BUILDING-BLOCKS SBBS; HIGH METHANE UPTAKE; CARBON-DIOXIDE; PORE-SIZE; HYDROGEN; SITES; GAS; STORAGE; LIGAND; CO2;
D O I：
10.1021/cg400449c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A porous metal organic framework [Cu-6(BDPP)(3)(H2O)(6)] (BDPP = 3,5-bis(3,5-dicarboxylphenyl)pyridine) (NJU-Bai10) was synthesized. NJU-Bai10 exhibits a high BET surface area of 2883 m(2) g(-1), the highest excess H-2 volumetric adsorption of 48.0 g L-1 (60 bar, 77 K), and a high methane uptake of 198.6 cm(3) cm(-3) that surpasses the DOE target.
引用
收藏
页码：2252 / 2255
页数：4
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