A new metal-organic framework for separation of C2H2/CH4 and CO2/CH4 at room temperature

被引：25
|
作者：
Duan, Xing [1 ]
Zhou, You [1 ]
Lv, Ran [1 ]
Yu, Ben [1 ]
Chen, Haodong [1 ]
Ji, Zhenguo [1 ]
Cui, Yuanjing [2 ]
Yang, Yu [2 ]
Qian, Guodong [2 ]
机构：
[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Sch Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2018年 / 260卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic frameworks; Porous materials; Crystal structure; Gas selective separation; CO2; SEPARATION; CARBON-DIOXIDE; ADSORPTION; FUNCTIONALIZATION; HYDROCARBONS; SELECTIVITY; ACETYLENE; CAPACITY; SORPTION; METHANE;
D O I：
10.1016/j.jssc.2018.01.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D microporous metal-organic framework with open Cu2+ sites and suitable pore space, [Cu-2(L)(H2O)(2)]center dot(H2O)(4)(DMF)(8) (ZJU-15, H4L = 5,5'-(9H-carbazole-2,7-diyl)diisophthalic acid; DMF = N,N-dimethylformamide; ZJU = Zhejiang University), has been constructed and characterized. The activated ZJU-15a has three different types of cages and exhibits BET surface area of 1660 m(2) g(-1), and can separate gas mixture of C2H2/CH4 and CO2/CH4 at room temperature.
引用
收藏
页码：31 / 33
页数：3
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