Design and Synthesis of Two Porous Metal-Organic Frameworks with nbo and agw Topologies Showing High CO2 Adsorption Capacity

被引:35
|
作者
Liang, Zhiqiang [1 ]
Du, Jingjing [1 ]
Sun, Libo [1 ]
Xu, Jin [1 ]
Mu, Ying [1 ]
Li, Yi [1 ]
Yu, Jihong [1 ]
Xu, Ruren [1 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON-DIOXIDE CAPTURE; LIQUID-PHASE ADSORPTION; HIGH H-2 ADSORPTION; COORDINATION POLYMERS; GAS SORPTION; ISORETICULAR SERIES; PORE-SIZE; STORAGE; SELECTIVITY; HYDROGEN;
D O I
10.1021/ic4017189
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two novel porous copper-based metal-organic frameworks with nbo and agw topologies have been designed and synthesized using tetracarboxylate and tricarboxylate ligands, respectively. They possess large surface areas and high CO2 adsorption capacities (up to 170 cm(3)/g or 7.59 mmol/g at 0 degrees C under ambient pressure).
引用
收藏
页码:10720 / 10722
页数:3
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