Crystal structure of (pyridine-kappa N)bis-(quinolin-2-olato-kappa N-2,O)copper(II) monohydrate

被引：0

作者：

Hawks, Benjamin ^{[1
]}

Yan, Jingjing ^{[1
]}

Basa, Prem ^{[1
]}

Burdette, Shawn ^{[1
]}

机构：

[1] Worcester Polytech Inst, Dept Chem & Biochem, 100 Inst Rd, Worcester, MA 01609 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; copper(II); quinolin-8-ol; pyridine; hydrogen bonding;

D O I：

10.1107/S2056989015001279

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Cu(C9H6NO)(2)(C5H4N)]center dot H2O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu-N bond of 2.305 (3) angstrom. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)degrees with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)degrees indicates near planarity. The water molecule connects adjacent copper complexes through O-H center dot center dot center dot O hydrogen bonds to phenolate O atoms, forming a network interconnecting all the complexes in the crystal lattice.

引用

页码：M38 / U176

页数：10

共 50 条

[1] (Ethylenediamine-kappa N-2,N ')bis(perchlorato-kappa O)bis(pyridine-kappa N)copper(II)
Ourari, Ali
Bounab, Nawel
Bouacida, Sofiane
Aggoun, Djouhra
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1030 - +
[2] Bis[2-(2-hydroxymethyl) pyridine-kappa N-2,O](pivalato-kappa O) copper(II)
Shaikh, M. Mobin
Mishra, Veenu
Ram, Priti
Birla, Anil
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1055 - +
[3] Bis[5-chloro-2-(phenyldiazenyl-kappa N-2)pyridine-kappa N]bis(thiocyanato-kappa N)iron(II)
Vittaya, Luksamee
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Hansongnern, Kanidtha
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M555 - U473
[4] Crystal structure of bis(acetato-kappa O)bis(pyridine-kappa(2)carboxamide oxime-kappa(2) N, N') cadmium ethanol disolvate
Liu, Jiyong
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 142 - +
[5] Crystal structure of poly[[mu-4-(hydroxymethyl)pyridine-kappa N-2:O][4-(hydroxy-methyl)pyridine-kappa N](mu-thiocyanato-kappa N-2:S)(thiocyanato-kappa N)cadmium]
Werner, Julia
Jess, Inke
Naether, Christian
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M129 - U78
[6] catena-Poly[[(2-{[2-(dimethylammonio)-ethyl]iminomethyl}pyridine-kappa N-2, N')bis-(thiocyanato-kappa N)manganese(II)]-mu-thiocyanato-kappa N-2:S]
Wang, Jun
Zhu, Wubiao
Li, Jichang
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1131 - +
[7] Bis(acetylacetonato-kappa O-2,O ')bis(pyridine-kappa N)nickel(II) dihydrate
Boutebdja, Mehdi
Beghidja, Adel
Beghidja, Chahrazed
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M131 - +
[8] Crystal structure of bis[4-(dimethylamino)pyridine-kappa N'] bis(methanol-kappa O)bis(thiocyanato-kappa N)manganese(II)
Suckert, Stefan
Jess, Inke
Naether, Christian
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M126 - U195
[9] cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-kappa N-2,O}bis(pyridine-kappa N)nickel(II)
Souza, Marcela C. G.
Ferreira, Leonardo da C.
Comerlato, Nadia M.
Ferreira, Glaucio B.
do Canto Visentin, Lorenzo
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1470 - +
[10] Bis(acetato-kappa O)bis(pyridine-2-aldoxime-kappa N-2, N ') nickel(II)
Si, Youtao
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M554 - +

← 1 2 3 4 5 →