Crystal structure of (pyridine-kappa N)bis-(quinolin-2-olato-kappa N-2,O)copper(II) monohydrate

被引：0
|
作者：
Hawks, Benjamin [1 ]
Yan, Jingjing [1 ]
Basa, Prem [1 ]
Burdette, Shawn [1 ]
机构：
[1] Worcester Polytech Inst, Dept Chem & Biochem, 100 Inst Rd, Worcester, MA 01609 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; copper(II); quinolin-8-ol; pyridine; hydrogen bonding;
D O I：
10.1107/S2056989015001279
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Cu(C9H6NO)(2)(C5H4N)]center dot H2O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu-N bond of 2.305 (3) angstrom. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)degrees with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)degrees indicates near planarity. The water molecule connects adjacent copper complexes through O-H center dot center dot center dot O hydrogen bonds to phenolate O atoms, forming a network interconnecting all the complexes in the crystal lattice.
引用
收藏
页码：M38 / U176
页数：10
相关论文
共 50 条
  • [11] Bis(benzene-1,2-diamine-kappa N-2,N ')-(sulfato-kappa O) copper(II) monohydrate
    Djebli, Yacine
    Boufas, Sihem
    Bencharif, Leila
    Roisnel, Thierry
    Bencharif, Mustafa
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1411 - +
  • [12] Bis(dicyanamido-kappa N)tetrakis(pyridine-kappa N)nickel(II)
    Woehlert, Susanne
    Wriedt, Mario
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M745 - +
  • [13] Diaquabis(nitrato-kappa O)bis(pyridine-kappa N)manganese(II)
    Alam, Naveed
    Shahid, Muhammad
    Rauf, M. Khawar
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M9 - +
  • [14] The non-centrosymmetric polymorph of (quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O) silver(I)
    Jia, Zhen-Bin
    Zhao, Yi
    Wen, Qiu-Jia
    Ma, Ai-Qing
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M133 - +
  • [15] Tetrakis(pyridine-kappa N)bis(tetrafluorido-borato-kappa F)copper(II)
    De Silva, Nirosha
    Pannu, Ajay Pal Singh
    Plieger, Paul G.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M450 - +
  • [16] Bis(2,2 '-bipyridyl-kappa N-2,N ')bis-(dicyanamido-kappa N)manganese(II)
    Wang, Haixia
    Wang, Shaohong
    Lang, Yuehe
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M569 - +
  • [17] Aquabis(4-chlorobenzoato)-kappa O-2,O'; kappa O-bis(pyridine-kappa N)cobalt(II)
    Chen, Ya-Li
    Zhang, Chun-E
    Fei, Peng
    Deng, Chao
    Su, Bi-Tao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M210 - +
  • [18] Crystal structure of (nitrato-kappa O)bis(1,10 '-phenanthroline-kappa N-2,N ')copper(II) nitrate gallic acid monosolvate monohydrate
    Shen, Fwu Ming
    Lush, Shie Fu
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1577 - +
  • [19] Crystal structure of trans-difluoridotetrakis-(pyridine-kappa N)chromium(III) trichlorido(pyridine-kappa N)zincate monohydrate from synchrotron data
    Moon, Dohyun
    Choi, Jong-Ha
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 290 - +
  • [20] Diaquabis[2-(2-hydroxyethyl)pyridine-kappa N-2,O]cobalt(II) dichloride
    Zeghouan, Ouahida
    Guenifa, Fatiha
    Hadjadj, Nasreddine
    Bendjeddou, Lamia
    Merazig, Hocine
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M439 - +
12345