Bis(acetato-kappa O)bis(pyridine-2-aldoxime-kappa N-2, N ') nickel(II)

被引：4
|
作者：
Si, Youtao [1 ]
机构：
[1] Univ Bretagne Occidentale, Univ Europeenne Bretagne, CS 93837, F-29238 Brest 3, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812014377
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the mononuclear title compound, [Ni(CH3COO)(2-)(C6H6N2O)(2)], the Ni-II atom is coordinated by two pyridine2- aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni-II atom by one O atom, each PaoH chelates the Ni-II atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni-II atom. Thus, the Ni-II atom exhibits an octahedral environment. Intramolecular O-H center dot center dot center dot O hydrogen-bonding interactions and intermolecular CH center dot center dot center dot O hydrogen-bonding interactions are present in the structure. Adjacent molecules pack along [100] through van der Waals forces.
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收藏
页码：M554 / +
页数：8
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