Crystal structure of bis(1,3-diaminopropane kappa N-2, N') bis[2-(4-nitrophenyl) acetato-kappa O] cadmium

被引：1

作者：

Rahn, Ian M. ^{[1
]}

Crawford, Carlos L. ^{[2
]}

Assefa, Zerihun ^{[2
]}

Hendrich, Jeffery ^{[3
]}

Sykora, Richard E. ^{[3
]}

机构：

[1] Univ N Carolina, Chapel Hill, NC 27515 USA

[2] N Carolina Agr & Tech State Univ, Dept Chem, 1601 E Market St, Greensboro, NC 27411 USA

[3] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

基金：

美国国家科学基金会;

关键词：

crystal structure; cadmium complex; 1,3-diaminopropane; nitrophenylacetic acid;

D O I：

10.1107/S2056989016000943

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title compound, [Cd(C8H6NO4)(2)(C3H10N2)(2)], the Cd-II atom is located on a center of symmetry with one independent Cd-O distance of 2.3547 (17) angstrom and two Cd-N distances of 2.3265 (18) and 2.3449 (19) angstrom. The Cd II atom has an overall octahedral coordination environment. Several types of hydrogen-bonding interactions are evident. Both intra-and intermolecular interactions occur between the amino groups and the O atoms of the acetate group. These N-H center dot center dot center dot O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak intermolecular C-H center dot center dot center dot O interactions involving the nitro groups exist, leading to the formation of a three-dimensional network structure.

引用

页码：226 / +

页数：8

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