Crystal structure of bis(1,3-diaminopropane kappa N-2, N') bis[2-(4-nitrophenyl) acetato-kappa O] cadmium

被引：1
|
作者：
Rahn, Ian M. [1 ]
Crawford, Carlos L. [2 ]
Assefa, Zerihun [2 ]
Hendrich, Jeffery [3 ]
Sykora, Richard E. [3 ]
机构：
[1] Univ N Carolina, Chapel Hill, NC 27515 USA
[2] N Carolina Agr & Tech State Univ, Dept Chem, 1601 E Market St, Greensboro, NC 27411 USA
[3] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
基金：
美国国家科学基金会;
关键词：
crystal structure; cadmium complex; 1,3-diaminopropane; nitrophenylacetic acid;
D O I：
10.1107/S2056989016000943
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the structure of the title compound, [Cd(C8H6NO4)(2)(C3H10N2)(2)], the Cd-II atom is located on a center of symmetry with one independent Cd-O distance of 2.3547 (17) angstrom and two Cd-N distances of 2.3265 (18) and 2.3449 (19) angstrom. The Cd II atom has an overall octahedral coordination environment. Several types of hydrogen-bonding interactions are evident. Both intra-and intermolecular interactions occur between the amino groups and the O atoms of the acetate group. These N-H center dot center dot center dot O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak intermolecular C-H center dot center dot center dot O interactions involving the nitro groups exist, leading to the formation of a three-dimensional network structure.
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页码：226 / +
页数：8
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