(Ethylenediamine-kappa N-2,N ')bis(perchlorato-kappa O)bis(pyridine-kappa N)copper(II)

被引：0
|
作者：
Ourari, Ali [1 ]
Bounab, Nawel [1 ]
Bouacida, Sofiane [2 ]
Aggoun, Djouhra [1 ]
机构：
[1] Univ Farhat Abbas, Fac Sci Ingn, LEIMCR, Setif 19000, Algeria
[2] Univ Mentouri Constantine, Unite Rech Chim Environnement & Mol Struct CHEMS, Constantine 25000, Algeria
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 19.4; mean σ(C-C) = 0.004 Å; R factor = 0.047; single-crystal X-ray study; T = 295 K; wR factor = 0.136;
D O I：
10.1107/S1600536812029868
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(ClO4)(2)(C2H8N2)(C5H5N)(2)], the Cu-II cation is located on a twofold rotation axis and is coordinated by four N and two O atoms in a tetragonally distorted octahedral geometry. The crystal packing can be described as ClO4 tetrahedra and CuN4O2 octahedra alternating in a zigzag fashion along the c axis. The structure is stabilized by intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, as well as pi-pi interactions [centroid-centroid distance = 3.7179 (15) angstrom].
引用
收藏
页码：M1030 / +
页数：8
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