Crystal structure of bis[4-(dimethylamino)pyridine-kappa N'] bis(methanol-kappa O)bis(thiocyanato-kappa N)manganese(II)

被引：1
|
作者：
Suckert, Stefan [1 ]
Jess, Inke [1 ]
Naether, Christian [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; discrete complex; octahedral coordination; hydrogen bonding;
D O I：
10.1107/S2056989015007318
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The whole molecule of the title compound, [Mn(NCS)(2)(CH3OH)(2)(C5H6N2)(2)], is generated by inversion symmetry. The Mn" ion, which is located on an inversion center, is coordinated by two 4-(dimethylamino)pyridine ligands, two methanol ligands and two terminally N-bonded thiocyanate anions, forming a slightly distorted octahedron. In the crystal, molecules are linked by O-H center dot center dot center dot S hydrogen bonds, forming chains extending along the a-axis direction.
引用
收藏
页码：M126 / U195
页数：6
相关论文
共 50 条
  • [1] Bis(3-acetylpyridine-kappa N)bis(methanol-kappa O)bis(thiocyanato-kappa N)nickel(II)
    Werner, Julia
    Boeckmann, Jan
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M441 - +
  • [2] Crystal structure of bis(3,5-dimethylpyridine-kappa N)bis(methanol-kappa O)bis(thiocyanato-kappa N)cobalt(II)
    Suckert, Stefan
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1824 - +
  • [3] Crystal structure of bis[4-(4-chlorobenz-yl)pyridine-kappa N]bis(thiocyanato-kappa N)zinc
    Werner, Julia
    Neumann, Tristan
    Jess, Inke
    Nather, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M355 - +
  • [4] Bis[4-(dimethylamino)pyridinium]bis[4-(dimethylamino)pyridine-kappa N-1]tetrakis-(thiocyanato-kappa N)manganate(II)
    Woehlert, Susanne
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1528 - +
  • [5] Crystal structure of bis(4-acetylpyridine-kappa N)bis(ethanol-kappa O)bis(thiocyanato-kappa N)-manganese(II)
    Werner, Julia
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M81 - U77
  • [6] Crystal structures of tetrakis(pyridine-4-thioamide-kappa N)bis(thiocyanato-kappa N)cobalt(II) monohydrate and bis(pyridine-4-thioamide-kappa N)bis(thiocyanato-kappa N)zinc(II)
    Neumann, Tristan
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 141 - +
  • [7] Bis(azido-kappa N) bis[4-(dimethylamino)-pyridine-kappa N]zinc
    Guenifa, Fatiha
    Hadjadj, Nasreddine
    Zeghouan, Ouahida
    Bendjeddou, Lamia
    Merazig, Hocine
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M169 - +
  • [8] Bis[5-chloro-2-(phenyldiazenyl-kappa N-2)pyridine-kappa N]bis(thiocyanato-kappa N)iron(II)
    Vittaya, Luksamee
    Leesakul, Nararak
    Pakawatchai, Chaveng
    Saithong, Saowanit
    Hansongnern, Kanidtha
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M555 - U473
  • [9] Crystal structures of (acetonitrile-kappa N)tris(pyridine-4-thioamide-kappa N)bis(thiocyanato-kappa N)cobalt(II) acetonitrile disolvate and tetrakis(pyridine-4-thioamide-kappa N)bis(thiocyanato-kappa N)nickel(II) methanol pentasolvate
    Neumann, Tristan
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 964 - +
  • [10] Crystal structures of bis[4-(dimethylamino)-pyridinium] tetrakis(thiocyanato-kappa N)manganate(II) and tris[4-(dimethylamino) pyridinium]pentakis-(thiocyanato-kappa N)manganate(II)
    Neumann, Tristan
    Jess, Inke
    Naether, Christian
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 15 - +
12345