Crystal structure of bis[4-(dimethylamino)pyridine-kappa N'] bis(methanol-kappa O)bis(thiocyanato-kappa N)manganese(II)

被引：1
|
作者：
Suckert, Stefan [1 ]
Jess, Inke [1 ]
Naether, Christian [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; discrete complex; octahedral coordination; hydrogen bonding;
D O I：
10.1107/S2056989015007318
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The whole molecule of the title compound, [Mn(NCS)(2)(CH3OH)(2)(C5H6N2)(2)], is generated by inversion symmetry. The Mn" ion, which is located on an inversion center, is coordinated by two 4-(dimethylamino)pyridine ligands, two methanol ligands and two terminally N-bonded thiocyanate anions, forming a slightly distorted octahedron. In the crystal, molecules are linked by O-H center dot center dot center dot S hydrogen bonds, forming chains extending along the a-axis direction.
引用
收藏
页码：M126 / U195
页数：6
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