PHASE-EQUILIBRIA OF SWOLLEN NEMATIC ELASTOMERS

被引：42
|
作者：
WARNER, M
WANG, XJ
机构：
[1] Cavendish Laboratory, Cambridge CB3 0HE, Madingley Road
来源：
MACROMOLECULES | 1992年 / 25卷 / 01期
关键词：
D O I：
10.1021/ma00027a069
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We calculate the phse diagram of a nematic network of covalently bonded semiflexible polymers swollen by isotropic solvent. At lower temperatures a nematic gel coexists with excess solvent; at high temperatures the coexisting gel is isotropic. In addition, coexistence is predicted between nematic and isotropic gel phases. There is an associated triple point. Possible elastic problems arise when different phases coexist in one gel sample.
引用
收藏
页码：445 / 449
页数：5
相关论文
共 50 条
  • [41] PHASE-EQUILIBRIA OF RICHTERITE AND FERRORICHTERITE
    CHARLES, RW
    AMERICAN MINERALOGIST, 1975, 60 (5-6) : 367 - 374
  • [42] PHASE-EQUILIBRIA OF POLYSTYRENE SOLUTIONS
    TAGER, AA
    ANDREEVA, VM
    VSHIVKOV, SA
    TJUKOVA, IS
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER SYMPOSIUM, 1977, (61): : 283 - 289
  • [43] NEMATIC-ISOTROPIC PHASE-EQUILIBRIA IN BINARY-MIXTURES CONTAINING RIGID ROD SOLUTES
    MARTIRE, DE
    DOWELL, F
    JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (12): : 5914 - 5915
  • [44] CALCULATION OF NEMATIC-ISOTROPIC PHASE-EQUILIBRIA IN SOLUTIONS OF POLYMERS IN NEMATIC LIQUID-CRYSTALS USING THE FLORY LATTICE MODEL
    BALLAUFF, M
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (11): : 1053 - 1058
  • [45] Deformation coupled to director rotation in swollen nematic elastomers under electric fields
    Urayama, K
    Honda, S
    Takigawa, T
    MACROMOLECULES, 2006, 39 (05) : 1943 - 1949
  • [46] Electro-optical effect coupled with macroscopic deformation of swollen nematic Elastomers
    Urayama, Kenji
    Fukunaga, Atsushi
    Kobayashi, Ichiro
    Takigawa, T-Oshikazu
    LIQUID CRYSTALS XI, 2007, 6654
  • [47] Phase Diagrams of Semisoft Nematic Elastomers
    Ye, Fangfu
    Lubensky, T. C.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (12): : 3853 - 3872
  • [48] On the phase equilibria of nematic mixtures
    Benmouna, F
    Maschke, U
    Coqueret, X
    Benmouna, M
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2000, 38 (03) : 478 - 485
  • [49] REQUISITES FOR RELIABLE DETERMINATION OF PHASE-EQUILIBRIA
    SMITH, JF
    MATERIALS SCIENCE AND ENGINEERING, 1981, 48 (01): : P1 - P7
  • [50] MODELING PHASE-EQUILIBRIA FOR THE MANUFACTURING OF REFRIGERANTS
    ANDERKO, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 24 - IEC
12345