PHASE-EQUILIBRIA OF SWOLLEN NEMATIC ELASTOMERS

被引：42
|
作者：
WARNER, M
WANG, XJ
机构：
[1] Cavendish Laboratory, Cambridge CB3 0HE, Madingley Road
来源：
MACROMOLECULES | 1992年 / 25卷 / 01期
关键词：
D O I：
10.1021/ma00027a069
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We calculate the phse diagram of a nematic network of covalently bonded semiflexible polymers swollen by isotropic solvent. At lower temperatures a nematic gel coexists with excess solvent; at high temperatures the coexisting gel is isotropic. In addition, coexistence is predicted between nematic and isotropic gel phases. There is an associated triple point. Possible elastic problems arise when different phases coexist in one gel sample.
引用
收藏
页码：445 / 449
页数：5
相关论文
共 50 条
  • [21] PHASE-EQUILIBRIA IN POLYDISPERSE FLUIDS
    STAPLETON, MR
    TILDESLEY, DJ
    QUIRKE, N
    JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (07): : 4456 - 4467
  • [22] PHASE-EQUILIBRIA UNDER STRESS
    CAHN, RW
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (08): : 1128 - 1130
  • [23] PHASE-EQUILIBRIA IN THE PYROXENE QUADRILATERAL
    SAXENA, SK
    SYKES, J
    ERIKSSON, G
    JOURNAL OF PETROLOGY, 1986, 27 (04) : 843 - 852
  • [24] PHASE-EQUILIBRIA AND THERMODYNAMICS - MEASUREMENTS
    KOMAREK, KL
    IPSER, H
    PURE AND APPLIED CHEMISTRY, 1984, 56 (11) : 1511 - 1526
  • [25] PHASE-EQUILIBRIA IN RADIATED ALLOYS
    BAKAI, AS
    TURKIN, AA
    PISMA V ZHURNAL TEKHNICHESKOI FIZIKI, 1987, 13 (21): : 1281 - 1283
  • [26] CALCULATION OF COHERENT PHASE-EQUILIBRIA
    WILLIAMS, RO
    JOURNAL OF METALS, 1983, 35 (12): : 15 - 15
  • [27] PHASE-EQUILIBRIA IN POLYMER MANUFACTURE
    BONNER, DC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 90 - &
  • [28] PHASE-EQUILIBRIA IN FLUID SYSTEMS
    SCHNEIDER, GM
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1984, 88 (09): : 841 - 848
  • [29] PHASE-EQUILIBRIA IN POLYDISPERSE FLUIDS
    GUALTIERI, JA
    KINCAID, JM
    MORRISON, G
    JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (01): : 521 - 536
  • [30] PHASE-EQUILIBRIA PROGRAM - AN UPDATE
    不详
    AMERICAN CERAMIC SOCIETY BULLETIN, 1987, 66 (04): : 630 - 631
12345