Phase Diagrams of Semisoft Nematic Elastomers

被引:13
|
作者
Ye, Fangfu [1 ]
Lubensky, T. C. [2 ]
机构
[1] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
[2] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 12期
基金
美国国家科学基金会;
关键词
LIQUID-CRYSTAL ELASTOMERS; STRIPE-DOMAINS; BEHAVIOR; REORIENTATION; DEFORMATION; TRANSITIONS; INSTABILITY; ANISOTROPY; FIELDS; GELS;
D O I
10.1021/jp8082002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nematic elastomers with locked-in anisotropy direction exhibit semisoft elastic response characterized by a plateau in the stress-strain curve in which stress does not change with strain. We calculate the global phase diagram for a minimal model, which is equivalent to one describing a nematic in crossed electric and magnetic fields, and show that semisoft behavior is associated with a broken symmetry biaxial phase and that it persists well into the supercritical regime. We also consider generalizations beyond the minimal model, particularly the neo-classical model introduced by Warner, Bladon, and Terentjev, and find similar results. Our work underscores the fact that semisoft response is fundamentally a nonlinear phenomenon and that experiments on samples at zero external stress provide no information about it.
引用
收藏
页码:3853 / 3872
页数:20
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