Phase Diagrams of Semisoft Nematic Elastomers

被引:13
|
作者
Ye, Fangfu [1 ]
Lubensky, T. C. [2 ]
机构
[1] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
[2] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 12期
基金
美国国家科学基金会;
关键词
LIQUID-CRYSTAL ELASTOMERS; STRIPE-DOMAINS; BEHAVIOR; REORIENTATION; DEFORMATION; TRANSITIONS; INSTABILITY; ANISOTROPY; FIELDS; GELS;
D O I
10.1021/jp8082002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nematic elastomers with locked-in anisotropy direction exhibit semisoft elastic response characterized by a plateau in the stress-strain curve in which stress does not change with strain. We calculate the global phase diagram for a minimal model, which is equivalent to one describing a nematic in crossed electric and magnetic fields, and show that semisoft behavior is associated with a broken symmetry biaxial phase and that it persists well into the supercritical regime. We also consider generalizations beyond the minimal model, particularly the neo-classical model introduced by Warner, Bladon, and Terentjev, and find similar results. Our work underscores the fact that semisoft response is fundamentally a nonlinear phenomenon and that experiments on samples at zero external stress provide no information about it.
引用
收藏
页码:3853 / 3872
页数:20
相关论文
共 50 条
  • [21] Phase diagrams of orientational transitions in absorbing nematic liquid crystals
    Zolot'ko, A. S.
    Ochkin, V. N.
    Smayev, M. P.
    Shvetsov, S. A.
    JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS, 2015, 120 (05) : 905 - 911
  • [22] PHASE-DIAGRAMS OF NEW COMPOUNDS WITH NEMATIC REENTRANT MESOPHASES
    TINH, NH
    ZANN, A
    DUBOIS, JC
    BILLARD, J
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1980, 56 (10): : 323 - 330
  • [23] Phase diagrams of orientational transitions in absorbing nematic liquid crystals
    A. S. Zolot’ko
    V. N. Ochkin
    M. P. Smayev
    S. A. Shvetsov
    Journal of Experimental and Theoretical Physics, 2015, 120 : 905 - 911
  • [24] PHASE-DIAGRAMS WITH CLOSED-LOOP SMECTIC - NEMATIC PHASE BOUNDARIES
    ILLIAN, G
    KNEPPE, H
    SCHNEIDER, F
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (07): : 776 - 780
  • [25] Dynamic Pressure Sensitive Adhesion in Nematic Phase of Liquid Crystal Elastomers
    Farre-Kaga, Hiro J.
    Saed, Mohand O.
    Terentjev, Eugene M.
    ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (12)
  • [26] Nematic elastomers: The dependence of phase transformation and orientation processes on crosslinking topology
    Greve, A
    Finkelmann, H
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (14) : 2926 - 2946
  • [27] Prediction of disclinations in nematic elastomers
    Fried, E
    Todres, RE
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (26) : 14773 - 14777
  • [28] Material instabilities in nematic elastomers
    DeSimone, A
    Dolzmann, G
    PHYSICA D, 2000, 136 (1-2): : 175 - 191
  • [29] Piezoelectricity of chiral nematic elastomers
    E.M. Terentjev
    M. Warner
    The European Physical Journal B - Condensed Matter and Complex Systems, 1999, 8 : 595 - 601
  • [30] ANALYSIS OF EXPERIMENTS ON NEMATIC ELASTOMERS
    VERWEY, GC
    WARNER, M
    MACROMOLECULES, 1995, 28 (12) : 4296 - 4298