UNTENONE-A, A NEW CYCLOPENTENONE FROM THE OKINAWAN MARINE SPONGE PLAKORTIS SP CORRESPONDING TO THE DIENOPHILE IN THE BIOSYNTHESIS OF MANZAMENONES

被引：43
|
作者：
ISHIBASHI, M [1 ]
TAKEUCHI, S [1 ]
KOBAYASHI, J [1 ]
机构：
[1] HOKKAIDO UNIV, FAC PHARMACEUT SCI, SAPPORO, HOKKAIDO 060, JAPAN
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 23期
关键词：
D O I：
10.1016/S0040-4039(00)79217-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Untenone A (1), a new cyclopentenone derivative was isolated from the Okinawan marine sponge Plakortis sp. This compound (1) is chemically equivalent to the hypothetical dienophile in biosynthesis of manzamenones and this isolation provides a substantiation for the proposed biosynthetic process of manzamenones involving intermolecular [4+2] cycloaddition reaction.
引用
收藏
页码：3749 / 3750
页数：2
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