5,10,15,20-TETRAKIS(P-CHLOROPHENYL)-PORPHYRIN

被引：12

作者：

HOKELEK, T ^{[1
]}

ULKU, D ^{[1
]}

GUNDUZ, N ^{[1
]}

HAYVALI, M ^{[1
]}

KILIC, Z ^{[1
]}

机构：

[1] UNIV ANKARA,DEPT CHEM,ANKARA,TURKEY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193000782

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title molecule, 2,7,12,17-tetrakis(4-chloro-phenyl)-21,22,23,24-tetraazapentacyclo[I 6.2. 1.1(3,6.-1(8,11.)1(13,16]tetracosa-1,3(22),4,6,8,10,12,14,16(4),17,-19-undecaene, is crystallographically centrosymmetric and the dihedral angle between the two pyrrole ring planes is 5.0 (4)-degrees . The molecular structure is a consequence of steric hinderances between the a-H atoms of the pyrrole and the ortho-H atoms of the phenyl rings. The dihedral angles between the pyrrole and phenyl rings are 54.8 (4) and 111. 1 (3)-degrees, respectively. The sums of the angles around meso-C atoms are -360-degrees and the average bond length between meso and adjacent macrocyclic ring C atoms is 1.398 (6) angstrom.

引用

页码：1667 / 1670

页数：4

共 50 条

[11] 5,10,15,20-Tetrakis(diphenylmethyl)porphyrin - A nonplanar porphyrin with intermediate degree of ruffling
Runge, Steffen
Senge, Mathias O.
Ruhlandt-Senge, Karin
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1999, 54 (05): : 662 - 666
[12] 5,10,15,20-tetrakis(diphenylmethyl)porphyrin - A nonplanar porphyrin with intermediate degree of ruffling
Runge, S
Senge, MO
Ruhlandt-Senge, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (05): : 662 - 666
[13] Synthesis and nanostructures of 5,10,15,20-tetrakis(4-piperidyl) porphyrin
Jacobsen, John L.
Berget, Patrick E.
Varela, Michael C.
Vu, Tony
Schore, Neil E.
Martin, Kathleen E.
Shelnutt, John A.
Santos, Luis M.
Medforth, Craig J.
TETRAHEDRON, 2013, 69 (48) : 10507 - 10515
[14] 131I-labeled 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin and 5,10,15,20-tetrakis(4-aminophenyl)porphyrin for combined photodynamic and radionuclide therapy
Song, Hu
Wang, Guanquan
Wang, Jing
Wang, Yunhan
Wei, Hongyuan
He, Jiaheng
Luo, Shunzhong
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2018, 316 (01) : 363 - 368
[15] 131I-labeled 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin and 5,10,15,20-tetrakis(4-aminophenyl)porphyrin for combined photodynamic and radionuclide therapy
Hu Song
Guanquan Wang
Jing Wang
Yunhan Wang
Hongyuan Wei
Jiaheng He
Shunzhong Luo
Journal of Radioanalytical and Nuclear Chemistry, 2018, 316 : 363 - 368
[16] SYNTHESIS AND CHARACTERIZATION OF 5,10,15,20-TETRAKIS(2-AMINO-5-CHLOROPHENYL)PORPHYRINS
LECAS, A
BOITREL, B
ROSE, E
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1991, (03): : 407 - 413
[17] From porphyrin benzylphosphoramidate conjugates to the catalytic hydrogenation of 5,10,15,20-tetrakis(pentafluorophenyl) porphyrin
de Souza, Marcos C.
Pedrosa, Leandro F.
Cazagrande, Gessica S.
Ferreira, Vitor F.
Neves, Maria G. P. M. S.
Cavaleiro, Jose A. S.
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2014, 10 : 628 - 633
[18] Effect of Solvent Polarity on the Spectral Characteristics of 5,10,15,20-Tetrakis(p-hydroxyphenyl)porphyrin
Guo, Hongwei
Liu, Xianhu
Li, Lan
Chang, Yanping
Yao, Wanqing
MOLECULES, 2023, 28 (14):
[19] Direct electrochemical synthesis of a nickel complex with 5,10,15,20-tetrakis(p-hydroxyphenyl) porphyrin
Blanco, Leonor M.
Gonzalez, Lucy T.
Kharisov, Boris I.
Aguilera, Elsa N.
Garnovskii, Alexander D.
Longoria, Francisco E.
Costamagna, Juan
Borodkin, G. S.
Korobov, M. S.
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2008, 38 (06) : 503 - 513
[20] Synthesis and Crystal Structure of α,α,β,β-5,10,15,20-Tetrakis(2-aminophenyl)porphyrin
矫志
王建辉
史秀丽
臧娜
刘阁
阮文娟
朱志昂
Chinese Journal of Structural Chemistry, 2008, (09) : 1103 - 1108

← 1 2 3 4 5 →