Synthesis and Crystal Structure of α,α,β,β-5,10,15,20-Tetrakis(2-aminophenyl)porphyrin

被引：0

作者：

矫志 ^{[1
]}

王建辉 ^{[1
]}

史秀丽 ^{[1
]}

臧娜 ^{[1
]}

刘阁 ^{[1
]}

阮文娟 ^{[1
]}

朱志昂 ^{[1
]}

机构：

[1] College of Chemistry,Nankai University

来源：

结构化学 | 2008年 / 09期

基金：

中国国家自然科学基金;

关键词：

porphyrin; crystal structure; N-H···π; interactions;

D O I：

10.14102/j.cnki.0254-5861.2008.09.021

中图分类号：

O626.13 [氮杂茂（吡咯）族];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound,α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin,has been obtained and characterized by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group C2/c with a = 31.804(6),b = 19.314(4),c = 12.872(3),β = 90.592(3)°,Z = 4,V = 7907(3) 3,Dc = 1.193 g/cm3,Mr = 1419.67,λ(MoKα) = 0.71073 ,μ = 0.073 mm-1,F(000) = 2984,R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of N-H···π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.

引用

页码：1103 / 1108

页数：6

共 50 条

[1] Synthesis and crystal structure of α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin
Jiao Zhi
Wang Jian-Hui
Shi Xiu-Li
Zang Na
Liu Ge
Ruan Wen-Juan
Zhu Zhi-Ang
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (09) : 1103 - 1108
[2] Synthesis and crystal structure of 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin
Bhyrappa, P
Suslick, KS
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 1998, 2 (4-5) : 391 - 396
[3] A KINETIC-STUDY OF THERMAL ROTATIONAL ISOMERIZATION OF 5,10,15,20-TETRAKIS(ORTHO-AMINOPHENYL)PORPHYRIN AND 5,10,15,20-TETRAKIS(ORTHO-PIVALOYLAMINOPHENYL)PORPHYRIN
HATANO, K
ANZAI, K
NISHINO, A
FUJII, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (12) : 3653 - 3654
[4] Electrochromic properties of conductive polyporphyrin films based on 5,10,15,20-tetrakis(4-aminophenyl)porphyrin and 5,10,15,20-tetrakis(4-pyridyl)porphyrin
Tesakova, Mariya, V
Syrbu, Sergey A.
Parfenyuk, Vladimir, I
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2022, 26 (12) : 853 - 861
[5] Synthesis, Crystal Structure and Electrochemical Property of 5,10,15,20-Tetrakis(4-chlorophenyl)porphyrin
Zhu Min
Lu Gui-Fen
Zhu Yu
Lv Ai-Xiang
Ou Zhong-Ping
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (07) : 921 - 924
[6] Synthesis, Crystal Structure and Electrochemical Property of 5,10,15,20-Tetrakis(4-chlorophenyl)porphyrin
朱敏
路桂芬
朱禹
吕爱香
欧忠平
结构化学, 2012, 31 (07) : 921 - 924
[7] 131I-labeled 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin and 5,10,15,20-tetrakis(4-aminophenyl)porphyrin for combined photodynamic and radionuclide therapy
Song, Hu
Wang, Guanquan
Wang, Jing
Wang, Yunhan
Wei, Hongyuan
He, Jiaheng
Luo, Shunzhong
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2018, 316 (01) : 363 - 368
[8] 131I-labeled 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin and 5,10,15,20-tetrakis(4-aminophenyl)porphyrin for combined photodynamic and radionuclide therapy
Hu Song
Guanquan Wang
Jing Wang
Yunhan Wang
Hongyuan Wei
Jiaheng He
Shunzhong Luo
Journal of Radioanalytical and Nuclear Chemistry, 2018, 316 : 363 - 368
[9] Adsorption of cobalt (II) 5,10,15,20-tetrakis(2-aminophenyl)-porphyrin onto copper substrates: Characterization and impedance studies for corrosion inhibition
Lokesh, Koodlur S.
De Keersmaecker, Michel
Elia, Alice
Depla, Diederik
Dubruel, Peter
Vandenabeele, Peter
Van Vlierberghe, Sandra
Adriaens, Annemie
CORROSION SCIENCE, 2012, 62 : 73 - 82
[10] Synthesis and nanostructures of 5,10,15,20-tetrakis(4-piperidyl) porphyrin
Jacobsen, John L.
Berget, Patrick E.
Varela, Michael C.
Vu, Tony
Schore, Neil E.
Martin, Kathleen E.
Shelnutt, John A.
Santos, Luis M.
Medforth, Craig J.
TETRAHEDRON, 2013, 69 (48) : 10507 - 10515

← 1 2 3 4 5 →