Synthesis and Crystal Structure of α,α,β,β-5,10,15,20-Tetrakis(2-aminophenyl)porphyrin

被引：0
|
作者：
矫志 [1 ]
王建辉 [1 ]
史秀丽 [1 ]
臧娜 [1 ]
刘阁 [1 ]
阮文娟 [1 ]
朱志昂 [1 ]
机构：
[1] College of Chemistry,Nankai University
来源：
结构化学 | 2008年 / 09期
基金：
中国国家自然科学基金;
关键词：
porphyrin; crystal structure; N-H···π; interactions;
D O I：
10.14102/j.cnki.0254-5861.2008.09.021
中图分类号：
O626.13 [氮杂茂（吡咯）族];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound,α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin,has been obtained and characterized by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group C2/c with a = 31.804(6),b = 19.314(4),c = 12.872(3),β = 90.592(3)°,Z = 4,V = 7907(3) 3,Dc = 1.193 g/cm3,Mr = 1419.67,λ(MoKα) = 0.71073 ,μ = 0.073 mm-1,F(000) = 2984,R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of N-H···π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.
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收藏
页码：1103 / 1108
页数：6
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