REACTIONS OF [RUH(CO)CL(EPH3)3] (E = P, AS) AND [RU(ETA-5-C5H5)CIL2] [L2 = (PPH3)2, (ASPH3)2, DPPE, DPPM] WITH 4-CYANOPYRIDINE, 1,4-DICYANOBENZENE AND 1,4-DICYANOBUTENE

被引：17

作者：

PANDEY, DS ^{[1
]}

MISHRA, RL ^{[1
]}

MISHRA, A ^{[1
]}

AGARWALA, UC ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

POLYHEDRON | 1990年 / 9卷 / 17期

关键词：

D O I：

10.1016/S0277-5387(00)84047-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [RuH(CO)Cl(EPh3)3] (E = P, As) with 4-cyanopyridine, 1,4-dicyanobenzene, 1,4-dicyanobutene and of [Ru(η5-C5H5)ClL2] [L2 = (PPh3)2, (AsPh3)2, dppe, dppm] with 1,4-dicyanobenzene in the presence of anions like BF4-, PF6-, BPh4-, ClO4-, have been carried out. Cyanopyridine containing hydridocarbonyl complexes showed a marked tendency to react with halogenated solvents yielding complexes containing no hydride ions. The cationic mononuclear, binuclear and neutral complexes have been characterized by elemental analyses and spectral (IR, UV-vis, 1H and 13C NMR) studies. © 1990.

引用

页码：2153 / 2162

页数：10

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