REACTIONS OF [RUH(CO)CL(EPH3)3] (E = P, AS) AND [RU(ETA-5-C5H5)CIL2] [L2 = (PPH3)2, (ASPH3)2, DPPE, DPPM] WITH 4-CYANOPYRIDINE, 1,4-DICYANOBENZENE AND 1,4-DICYANOBUTENE

被引：17
|
作者：
PANDEY, DS [1 ]
MISHRA, RL [1 ]
MISHRA, A [1 ]
AGARWALA, UC [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA
来源：
POLYHEDRON | 1990年 / 9卷 / 17期
关键词：
D O I：
10.1016/S0277-5387(00)84047-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of [RuH(CO)Cl(EPh3)3] (E = P, As) with 4-cyanopyridine, 1,4-dicyanobenzene, 1,4-dicyanobutene and of [Ru(η5-C5H5)ClL2] [L2 = (PPh3)2, (AsPh3)2, dppe, dppm] with 1,4-dicyanobenzene in the presence of anions like BF4-, PF6-, BPh4-, ClO4-, have been carried out. Cyanopyridine containing hydridocarbonyl complexes showed a marked tendency to react with halogenated solvents yielding complexes containing no hydride ions. The cationic mononuclear, binuclear and neutral complexes have been characterized by elemental analyses and spectral (IR, UV-vis, 1H and 13C NMR) studies. © 1990.
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页码：2153 / 2162
页数：10
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